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High performance anodes with tailored catalytic properties for La5.6WO11.4-d; based proton conducting fuel cells

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High performance anodes with tailored catalytic properties for La5.6WO11.4-d; based proton conducting fuel cells

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dc.contributor.author Balaguer Ramírez, María es_ES
dc.contributor.author Solis Díaz, Cecilia es_ES
dc.contributor.author Bozza, F. es_ES
dc.contributor.author Bonanos, N. es_ES
dc.contributor.author Serra Alfaro, José Manuel es_ES
dc.date.accessioned 2016-07-25T11:07:41Z
dc.date.available 2016-07-25T11:07:41Z
dc.date.issued 2013
dc.identifier.issn 0959-9428
dc.identifier.uri http://hdl.handle.net/10251/68089
dc.description.abstract This work shows the development of anodes based Sr-doped LaCrO3 (LSC) for La5.6WO11.4-d;-based proton conducting fuel cells. The electrode was improved by considering the operation limitations of the LSC material, which is chemically compatible at high temperatures with La5.6WO11.4-d; in contrast with typically NiO-based composite anodes. Firstly, the synthesis of 10% Ce doped LSC material, its compatibility with LWO and superior conduction properties are presented. These properties make this composition suitable as anode material, although EIS analysis revealed that its operation is still limited by LF surface associated limiting processes. In order to improve the surface catalytic properties of the anode, Ni infiltration was conducted on sintered anode, resulting in the coating of the electrode surface with Ni nanoparticles and consequently in a further improvement of the anode performance. Specifically, the infiltrated anode with the highest Ni loading presents uniquely HF associated resistance and the Rp is 0.26 ohm cm2 at 750 ºC in wet H2. es_ES
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Journal of Materials Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Anode es_ES
dc.subject Fuel cell es_ES
dc.subject SOFC es_ES
dc.subject Proton conductor es_ES
dc.subject Tungstate es_ES
dc.title High performance anodes with tailored catalytic properties for La5.6WO11.4-d; based proton conducting fuel cells es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c3ta01554h
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Balaguer Ramirez, M.; Solis Díaz, C.; Bozza, F.; Bonanos, N.; Serra Alfaro, JM. (2013). High performance anodes with tailored catalytic properties for La5.6WO11.4-d; based proton conducting fuel cells. Journal of Materials Chemistry. 1(9):3004-3007. doi:10.1039/c3ta01554h es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1039/c3ta01554h es_ES
dc.description.upvformatpinicio 3004 es_ES
dc.description.upvformatpfin 3007 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 1 es_ES
dc.description.issue 9 es_ES
dc.relation.senia 232746 es_ES
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