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Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution

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Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution

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Li, Z.; Martínez Triguero, LJ.; Concepción Heydorn, P.; Yu, J.; Corma Canós, A. (2013). Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution. Physical Chemistry Chemical Physics. 15(35):14670-14680. doi:10.1039/c3cp52247d

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Title: Methanol to olefins: activity and stability of nanosized SAPO-34 molecular sieves and control of selectivity by silicon distribution
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Universitat Politècnica de València. Departamento de Química - Departament de Química
Issued date:
Abstract:
[EN] Nano-SAPO-34 molecular sieves synthesized in a microwave environment with 20 nm crystal size showed a longer lifetime than SAPO-34 prepared by the conventional hydrothermal method in the reaction of methanol to olefins. ...[+]
Subjects: HYDROCARBON POOL MECHANISM , MESOPOROUS SSZ-13 ZEOLITE , MAS NMR-SPECTROSCOPY , SOLID-STATE NMR , MTO-REACTION , CATALYTIC PERFORMANCE , SILICOALUMINOPHOSPHATES H-SAPO-34 , THERMAL-STABILITY , COKE DEPOSITION , TEMPLATE METHOD
Copyrigths: Reserva de todos los derechos
Source:
Physical Chemistry Chemical Physics. (issn: 1463-9076 ) (eissn: 1463-9084 )
DOI: 10.1039/c3cp52247d
Publisher:
Royal Society of Chemistry
Publisher version: https://dx.doi.org/10.1039/c3cp52247d
Thanks:
Financial support by the Spanish MINECO (MAT2012-37160, CSD2009-00050-CONSOLIDER/INGENIO 2010), and Generalitat Valenciana by the PROMETEO program is acknowledged. Z. Li acknowledges China Scholarship Council (CSC) for a ...[+]
Type: Artículo

References

Bjørgen, M., Joensen, F., Spangsberg Holm, M., Olsbye, U., Lillerud, K.-P., & Svelle, S. (2008). Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH. Applied Catalysis A: General, 345(1), 43-50. doi:10.1016/j.apcata.2008.04.020

Vennestrøm, P. N. R., Grill, M., Kustova, M., Egeblad, K., Lundegaard, L. F., Joensen, F., … Beato, P. (2011). Hierarchical ZSM-5 prepared by guanidinium base treatment: Understanding microstructural characteristics and impact on MTG and NH3-SCR catalytic reactions. Catalysis Today, 168(1), 71-79. doi:10.1016/j.cattod.2011.03.045

Barbera, K., Bonino, F., Bordiga, S., Janssens, T. V. W., & Beato, P. (2011). Structure–deactivation relationship for ZSM-5 catalysts governed by framework defects. Journal of Catalysis, 280(2), 196-205. doi:10.1016/j.jcat.2011.03.016 [+]
Bjørgen, M., Joensen, F., Spangsberg Holm, M., Olsbye, U., Lillerud, K.-P., & Svelle, S. (2008). Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH. Applied Catalysis A: General, 345(1), 43-50. doi:10.1016/j.apcata.2008.04.020

Vennestrøm, P. N. R., Grill, M., Kustova, M., Egeblad, K., Lundegaard, L. F., Joensen, F., … Beato, P. (2011). Hierarchical ZSM-5 prepared by guanidinium base treatment: Understanding microstructural characteristics and impact on MTG and NH3-SCR catalytic reactions. Catalysis Today, 168(1), 71-79. doi:10.1016/j.cattod.2011.03.045

Barbera, K., Bonino, F., Bordiga, S., Janssens, T. V. W., & Beato, P. (2011). Structure–deactivation relationship for ZSM-5 catalysts governed by framework defects. Journal of Catalysis, 280(2), 196-205. doi:10.1016/j.jcat.2011.03.016

Na, K., Choi, M., & Ryoo, R. (2013). Recent advances in the synthesis of hierarchically nanoporous zeolites. Microporous and Mesoporous Materials, 166, 3-19. doi:10.1016/j.micromeso.2012.03.054

Jacobsen, C. J. H., Madsen, C., Houzvicka, J., Schmidt, I., & Carlsson, A. (2000). Mesoporous Zeolite Single Crystals. Journal of the American Chemical Society, 122(29), 7116-7117. doi:10.1021/ja000744c

Kim, J., Choi, M., & Ryoo, R. (2010). Effect of mesoporosity against the deactivation of MFI zeolite catalyst during the methanol-to-hydrocarbon conversion process. Journal of Catalysis, 269(1), 219-228. doi:10.1016/j.jcat.2009.11.009

Firoozi, M., Baghalha, M., & Asadi, M. (2009). The effect of micro and nano particle sizes of H-ZSM-5 on the selectivity of MTP reaction. Catalysis Communications, 10(12), 1582-1585. doi:10.1016/j.catcom.2009.04.021

Rownaghi, A. A., & Hedlund, J. (2011). Methanol to Gasoline-Range Hydrocarbons: Influence of Nanocrystal Size and Mesoporosity on Catalytic Performance and Product Distribution of ZSM-5. Industrial & Engineering Chemistry Research, 50(21), 11872-11878. doi:10.1021/ie201549j

Sommer, L., Mores, D., Svelle, S., Stöcker, M., Weckhuysen, B. M., & Olsbye, U. (2010). Mesopore formation in zeolite H-SSZ-13 by desilication with NaOH. Microporous and Mesoporous Materials, 132(3), 384-394. doi:10.1016/j.micromeso.2010.03.017

Wu, L., Degirmenci, V., Magusin, P. C. M. M., Szyja, B. M., & Hensen, E. J. M. (2012). Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction. Chemical Communications, 48(76), 9492. doi:10.1039/c2cc33994c

Wu, L., Degirmenci, V., Magusin, P. C. M. M., Lousberg, N. J. H. G. M., & Hensen, E. J. M. (2013). Mesoporous SSZ-13 zeolite prepared by a dual-template method with improved performance in the methanol-to-olefins reaction. Journal of Catalysis, 298, 27-40. doi:10.1016/j.jcat.2012.10.029

Schmidt, F., Paasch, S., Brunner, E., & Kaskel, S. (2012). Carbon templated SAPO-34 with improved adsorption kinetics and catalytic performance in the MTO-reaction. Microporous and Mesoporous Materials, 164, 214-221. doi:10.1016/j.micromeso.2012.04.045

Hirota, Y., Murata, K., Tanaka, S., Nishiyama, N., Egashira, Y., & Ueyama, K. (2010). Dry gel conversion synthesis of SAPO-34 nanocrystals. Materials Chemistry and Physics, 123(2-3), 507-509. doi:10.1016/j.matchemphys.2010.05.005

Lee, K. Y., Chae, H.-J., Jeong, S.-Y., & Seo, G. (2009). Effect of crystallite size of SAPO-34 catalysts on their induction period and deactivation in methanol-to-olefin reactions. Applied Catalysis A: General, 369(1-2), 60-66. doi:10.1016/j.apcata.2009.08.033

Lee, Y.-J., Baek, S.-C., & Jun, K.-W. (2007). Methanol conversion on SAPO-34 catalysts prepared by mixed template method. Applied Catalysis A: General, 329, 130-136. doi:10.1016/j.apcata.2007.06.034

Wang, P., Lv, A., Hu, J., Xu, J., & Lu, G. (2012). The synthesis of SAPO-34 with mixed template and its catalytic performance for methanol to olefins reaction. Microporous and Mesoporous Materials, 152, 178-184. doi:10.1016/j.micromeso.2011.11.037

Álvaro-Muñoz, T., Márquez-Álvarez, C., & Sastre, E. (2012). Use of different templates on SAPO-34 synthesis: Effect on the acidity and catalytic activity in the MTO reaction. Catalysis Today, 179(1), 27-34. doi:10.1016/j.cattod.2011.07.038

Lin, S., Li, J., Sharma, R. P., Yu, J., & Xu, R. (2010). Fabrication of SAPO-34 Crystals with Different Morphologies by Microwave Heating. Topics in Catalysis, 53(19-20), 1304-1310. doi:10.1007/s11244-010-9588-3

Shalmani, F. M., Halladj, R., & Askari, S. (2012). Effect of contributing factors on microwave-assisted hydrothermal synthesis of nanosized SAPO-34 molecular sieves. Powder Technology, 221, 395-402. doi:10.1016/j.powtec.2012.01.036

Yang, G., Wei, Y., Xu, S., Chen, J., Li, J., Liu, Z., … Xu, R. (2013). Nanosize-Enhanced Lifetime of SAPO-34 Catalysts in Methanol-to-Olefin Reactions. The Journal of Physical Chemistry C, 117(16), 8214-8222. doi:10.1021/jp312857p

Buchholz, A., Wang, W., Arnold, A., Xu, M., & Hunger, M. (2003). Successive steps of hydration and dehydration of silicoaluminophosphates H-SAPO-34 and H-SAPO-37 investigated by in situ CF MAS NMR spectroscopy. Microporous and Mesoporous Materials, 57(2), 157-168. doi:10.1016/s1387-1811(02)00562-0

Buchholz, A., Wang, W., Xu, M., Arnold, A., & Hunger, M. (2002). Thermal stability and dehydroxylation of Brønsted acid sites in silicoaluminophosphates H-SAPO-11, H-SAPO-18, H-SAPO-31, and H-SAPO-34 investigated by multi-nuclear solid-state NMR spectroscopy. Microporous and Mesoporous Materials, 56(3), 267-278. doi:10.1016/s1387-1811(02)00491-2

Blackwell, C. S., & Patton, R. L. (1988). Solid-state NMR of silicoaluminophosphate molecular sieves and aluminophosphate materials. The Journal of Physical Chemistry, 92(13), 3965-3970. doi:10.1021/j100324a055

Lok, B. M., Messina, C. A., Patton, R. L., Gajek, R. T., Cannan, T. R., & Flanigen, E. M. (1984). Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids. Journal of the American Chemical Society, 106(20), 6092-6093. doi:10.1021/ja00332a063

Vomscheid, R., Briend, M., Peltre, M. J., Man, P. P., & Barthomeuf, D. (1994). The Role of the Template in Directing the Si Distribution in SAPO Zeolites. The Journal of Physical Chemistry, 98(38), 9614-9618. doi:10.1021/j100089a041

Martins, G. A. V., Berlier, G., Coluccia, S., Pastore, H. O., Superti, G. B., Gatti, G., & Marchese, L. (2007). Revisiting the Nature of the Acidity in Chabazite-Related Silicoaluminophosphates:  Combined FTIR and29Si MAS NMR Study. The Journal of Physical Chemistry C, 111(1), 330-339. doi:10.1021/jp063921q

Wei, Y., Zhang, D., Xu, L., Chang, F., He, Y., Meng, S., … Liu, Z. (2008). Synthesis, characterization and catalytic performance of metal-incorporated SAPO-34 for chloromethane transformation to light olefins. Catalysis Today, 131(1-4), 262-269. doi:10.1016/j.cattod.2007.10.055

Briend, M., Vomscheid, R., Peltre, M. J., Man, P. P., & Barthomeuf, D. (1995). Influence of the Choice of the Template on the Short- and Long-Term Stability of SAPO-34 Zeolite. The Journal of Physical Chemistry, 99(20), 8270-8276. doi:10.1021/j100020a060

Suzuki, K., Nishio, T., Katada, N., Sastre, G., & Niwa, M. (2011). Ammonia IRMS-TPD measurements on Brønsted acidity of proton-formed SAPO-34. Phys. Chem. Chem. Phys., 13(8), 3311-3318. doi:10.1039/c0cp00961j

Katada, N., Nouno, K., Lee, J. K., Shin, J., Hong, S. B., & Niwa, M. (2011). Acidic Properties of Cage-Based, Small-Pore Zeolites with Different Framework Topologies and Their Silicoaluminophosphate Analogues. The Journal of Physical Chemistry C, 115(45), 22505-22513. doi:10.1021/jp207894n

Sastre, G., Lewis, D. W., & Catlow, C. R. A. (1997). Modeling of Silicon Substitution in SAPO-5 and SAPO-34 Molecular Sieves. The Journal of Physical Chemistry B, 101(27), 5249-5262. doi:10.1021/jp963736k

Barthomeuf, D. (1994). Topological model for the compared acidity of SAPOs and SiAl zeolites. Zeolites, 14(6), 394-401. doi:10.1016/0144-2449(94)90164-3

Buchholz, A., Wang, W., Xu, M., Arnold, A., & Hunger, M. (2004). Sequential Steps of Ammoniation of the Microporous Silicoaluminophosphates H-SAPO-34 and H-SAPO-37 Investigated by In Situ CF MAS NMR Spectroscopy. The Journal of Physical Chemistry B, 108(10), 3107-3113. doi:10.1021/jp030249d

Watanabe, Y., Koiwai, A., Takeuchi, H., Hyodo, S. A., & Noda, S. (1993). Multinuclear NMR Studies on the Thermal Stability of SAPO-34. Journal of Catalysis, 143(2), 430-436. doi:10.1006/jcat.1993.1287

BUSCA, G. (1991). FT-113 study of the surface properties of the spinels NiAl2O4 and CoAl2O4 in relation to those of transitional aluminas. Journal of Catalysis, 131(1), 167-177. doi:10.1016/0021-9517(91)90333-y

Busca, G., Lorenzelli, V., Ramis, G., & Willey, R. J. (1993). Surface sites on spinel-type and corundum-type metal oxide powders. Langmuir, 9(6), 1492-1499. doi:10.1021/la00030a012

Eilertsen, E. A., Arstad, B., Svelle, S., & Lillerud, K. P. (2012). Single parameter synthesis of high silica CHA zeolites from fluoride media. Microporous and Mesoporous Materials, 153, 94-99. doi:10.1016/j.micromeso.2011.12.026

Bordiga, S., Regli, L., Cocina, D., Lamberti, C., Bjørgen, M., & Lillerud, K. P. (2005). Assessing the Acidity of High Silica Chabazite H−SSZ-13 by FTIR Using CO as Molecular Probe:  Comparison with H−SAPO-34. The Journal of Physical Chemistry B, 109(7), 2779-2784. doi:10.1021/jp045498w

Bleken, F., Bjørgen, M., Palumbo, L., Bordiga, S., Svelle, S., Lillerud, K.-P., & Olsbye, U. (2009). The Effect of Acid Strength on the Conversion of Methanol to Olefins Over Acidic Microporous Catalysts with the CHA Topology. Topics in Catalysis, 52(3), 218-228. doi:10.1007/s11244-008-9158-0

Janssens, T. V. W. (2009). A new approach to the modeling of deactivation in the conversion of methanol on zeolite catalysts. Journal of Catalysis, 264(2), 130-137. doi:10.1016/j.jcat.2009.03.004

Chen, D., Rebo, H. P., Moljord, K., & Holmen, A. (1997). Influence of Coke Deposition on Selectivity in Zeolite Catalysis. Industrial & Engineering Chemistry Research, 36(9), 3473-3479. doi:10.1021/ie9700223

Sedran, U., Mahay, A., & De Lasa, H. I. (1990). Modelling methanol conversion to hydrocarbons: revision and testing of a simple kinetic model. Chemical Engineering Science, 45(5), 1161-1165. doi:10.1016/0009-2509(90)87109-6

Chen, D., Rebo, H. P., Moljord, K., & Holmen, A. (1997). The role of coke deposition in the conversion of methanol to olefins over SAPO-34. Studies in Surface Science and Catalysis, 159-166. doi:10.1016/s0167-2991(97)80151-6

Chen, D., Rebo, H. P., Moljord, K., & Holmen, A. (1999). Methanol Conversion to Light Olefins over SAPO-34. Sorption, Diffusion, and Catalytic Reactions. Industrial & Engineering Chemistry Research, 38(11), 4241-4249. doi:10.1021/ie9807046

Svelle, S., Sommer, L., Barbera, K., Vennestrøm, P. N. R., Olsbye, U., Lillerud, K. P., … Beato, P. (2011). How defects and crystal morphology control the effects of desilication. Catalysis Today, 168(1), 38-47. doi:10.1016/j.cattod.2010.12.013

Sazama, P., Wichterlova, B., Dedecek, J., Tvaruzkova, Z., Musilova, Z., Palumbo, L., … Gonsiorova, O. (2011). FTIR and 27Al MAS NMR analysis of the effect of framework Al- and Si-defects in micro- and micro-mesoporous H-ZSM-5 on conversion of methanol to hydrocarbons. Microporous and Mesoporous Materials, 143(1), 87-96. doi:10.1016/j.micromeso.2011.02.013

Chen, D., Grønvold, A., Moljord, K., & Holmen, A. (2007). Methanol Conversion to Light Olefins over SAPO-34:  Reaction Network and Deactivation Kinetics. Industrial & Engineering Chemistry Research, 46(12), 4116-4123. doi:10.1021/ie0610748

Dahl, I. M., Mostad, H., Akporiaye, D., & Wendelbo, R. (1999). Structural and chemical influences on the MTO reaction: a comparison of chabazite and SAPO-34 as MTO catalysts. Microporous and Mesoporous Materials, 29(1-2), 185-190. doi:10.1016/s1387-1811(98)00330-8

Hereijgers, B. P. C., Bleken, F., Nilsen, M. H., Svelle, S., Lillerud, K.-P., Bjørgen, M., … Olsbye, U. (2009). Product shape selectivity dominates the Methanol-to-Olefins (MTO) reaction over H-SAPO-34 catalysts. Journal of Catalysis, 264(1), 77-87. doi:10.1016/j.jcat.2009.03.009

Song, W., Fu, H., & Haw, J. F. (2001). Supramolecular Origins of Product Selectivity for Methanol-to-Olefin Catalysis on HSAPO-34. Journal of the American Chemical Society, 123(20), 4749-4754. doi:10.1021/ja0041167

Arstad, B., Nicholas, J. B., & Haw, J. F. (2004). Theoretical Study of the Methylbenzene Side-Chain Hydrocarbon Pool Mechanism in Methanol to Olefin Catalysis. Journal of the American Chemical Society, 126(9), 2991-3001. doi:10.1021/ja035923j

Zhou, H., Wang, Y., Wei, F., Wang, D., & Wang, Z. (2008). Kinetics of the reactions of the light alkenes over SAPO-34. Applied Catalysis A: General, 348(1), 135-141. doi:10.1016/j.apcata.2008.06.033

Chen, D., Moljord, K., & Holmen, A. (2012). A methanol to olefins review: Diffusion, coke formation and deactivation on SAPO type catalysts. Microporous and Mesoporous Materials, 164, 239-250. doi:10.1016/j.micromeso.2012.06.046

Wang, C.-M., Wang, Y.-D., & Xie, Z.-K. (2013). Insights into the reaction mechanism of methanol-to-olefins conversion in HSAPO-34 from first principles: Are olefins themselves the dominating hydrocarbon pool species? Journal of Catalysis, 301, 8-19. doi:10.1016/j.jcat.2013.01.024

Wang, C.-M., Wang, Y.-D., Xie, Z.-K., & Liu, Z.-P. (2009). Methanol to Olefin Conversion on HSAPO-34 Zeolite from Periodic Density Functional Theory Calculations: A Complete Cycle of Side Chain Hydrocarbon Pool Mechanism. The Journal of Physical Chemistry C, 113(11), 4584-4591. doi:10.1021/jp810350x

Hemelsoet, K., Van der Mynsbrugge, J., De Wispelaere, K., Waroquier, M., & Van Speybroeck, V. (2013). Unraveling the Reaction Mechanisms Governing Methanol-to-Olefins Catalysis by Theory and Experiment. ChemPhysChem, 14(8), 1526-1545. doi:10.1002/cphc.201201023

Westgård Erichsen, M., Svelle, S., & Olsbye, U. (2013). The influence of catalyst acid strength on the methanol to hydrocarbons (MTH) reaction. Catalysis Today, 215, 216-223. doi:10.1016/j.cattod.2013.03.017

Kim, S. J., Jang, H.-G., Lee, J. K., Min, H.-K., Hong, S. B., & Seo, G. (2011). Direct observation of hexamethylbenzenium radical cations generated during zeolite methanol-to-olefin catalysis: an ESR study. Chemical Communications, 47(33), 9498. doi:10.1039/c1cc13153b

Alberty, R. A., & Gehrig, C. A. (1985). Standard Chemical Thermodynamic Properties of Alkene Isomer Groups. Journal of Physical and Chemical Reference Data, 14(3), 803-820. doi:10.1063/1.555737

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