Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework
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https://riunet.upv.es/handle/10251/70157
Cita bibliográfica
Sastre Navarro, GI.; Van Den Bergh, J.; Kapteijn, F.; Denysenko, D.; Volkmer, D. (2014). Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework. Dalton Transactions. 43(25):9612-9619. https://doi.org/10.1039/c4dt00365a
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The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N-2.
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Dalton Transactions issn: 1477-9226