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Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework

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Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework

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Sastre Navarro, GI.; Van Den Bergh, J.; Kapteijn, F.; Denysenko, D.; Volkmer, D. (2014). Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework. Dalton Transactions. 43(25):9612-9619. doi:10.1039/c4dt00365a

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Title: Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework
Author: Sastre Navarro, German Ignacio van den Bergh, Johan Kapteijn, Freek Denysenko, Dmytro Volkmer, Dirk
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small ...[+]
Subjects: Metal-organic frameworks , Adsorption
Copyrigths: Reconocimiento (by)
Source:
Dalton Transactions. (issn: 1477-9226 )
DOI: 10.1039/c4dt00365a
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/c4dt00365a
Project ID:
Spanish government for the provision of Severo Ochoa project SEV 2012-0267
DFG SPP 1362
Thanks:
G. S. thanks the Spanish government for the provision of Severo Ochoa project (SEV 2012-0267) and SGAI-CSIC for computing time. Financial support by the DFG (Priority Program SPP 1362 "Porous Metal-organic Frameworks") is ...[+]
Type: Artículo

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