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dc.contributor.author | Sastre Navarro, German Ignacio | es_ES |
dc.contributor.author | van den Bergh, Johan | es_ES |
dc.contributor.author | Kapteijn, Freek | es_ES |
dc.contributor.author | Denysenko, Dmytro | es_ES |
dc.contributor.author | Volkmer, Dirk | es_ES |
dc.date.accessioned | 2016-09-20T11:34:03Z | |
dc.date.available | 2016-09-20T11:34:03Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/10251/70157 | |
dc.description.abstract | The metal-organic framework MFU-4 shows preferential adsorption of CO2 over N-2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N-2. | es_ES |
dc.description.sponsorship | G. S. thanks the Spanish government for the provision of Severo Ochoa project (SEV 2012-0267) and SGAI-CSIC for computing time. Financial support by the DFG (Priority Program SPP 1362 "Porous Metal-organic Frameworks") is gratefully acknowledged (D. V. and D. D.). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Dalton Transactions | es_ES |
dc.rights | Reconocimiento (by) | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Adsorption | es_ES |
dc.title | Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c4dt00365a | |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/ | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/DFG//SPP 1362/ | es_ES |
dc.rights.accessRights | Abierto | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Sastre Navarro, GI.; Van Den Bergh, J.; Kapteijn, F.; Denysenko, D.; Volkmer, D. (2014). Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal-organic framework. Dalton Transactions. 43(25):9612-9619. https://doi.org/10.1039/c4dt00365a | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c4dt00365a | es_ES |
dc.description.upvformatpinicio | 9612 | es_ES |
dc.description.upvformatpfin | 9619 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 43 | es_ES |
dc.description.issue | 25 | es_ES |
dc.relation.senia | 278054 | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad | es_ES |
dc.contributor.funder | Deutsche Forschungsgemeinschaft | es_ES |