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dc.contributor.author | Opanasenko, Maksym | es_ES |
dc.contributor.author | Dhakshinamoorthy, Amarajothi | es_ES |
dc.contributor.author | Shamzhy, Mariya | es_ES |
dc.contributor.author | Nachtigall, Petr | es_ES |
dc.contributor.author | Horacek, Michal | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Cejka, Jiri | es_ES |
dc.date.accessioned | 2016-10-11T06:45:25Z | |
dc.date.available | 2016-10-11T06:45:25Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 2044-4753 | |
dc.identifier.uri | http://hdl.handle.net/10251/71579 | |
dc.description.abstract | [EN] The catalytic behavior of metal-organic-frameworks (MOFs) CuBTC and FeBTC was investigated in Knoevenagel condensation of cyclohexane carbaldehyde and benzaldehyde with active methylene compounds and compared with zeolites BEA and TS-1. High yields were achieved over the CuBTC catalyst in the Knoevenagel condensation involving malonitrile, especially at a relatively low reaction temperature (80 degrees C); no leaching of the active phase was evidenced. In contrast, zeolites were not active under such reaction conditions. We propose an activation of malonitrile on a pair of adjacent Cu ions to explain the high catalytic activity of CuBTC with respect to conventional catalysts. Compared with CuBTC, zeolites exhibited usually lower selectivities, which is ascribed to a high acid strength of their active sites promoting consecutive reactions. | es_ES |
dc.description.sponsorship | The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 228862. P.N., M. H., and J.C. thank the Czech Grant Agency for the financial support (Centre of Excellence - P106/12/G015). | en_EN |
dc.language | Inglés | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.ispartof | Catalysis Science and Technology | es_ES |
dc.rights | Reserva de todos los derechos | es_ES |
dc.subject | BASE CATALYSTS | es_ES |
dc.subject | METAL-ORGANIC FRAMEWORKS | es_ES |
dc.subject | SOLVENT-FREE CONDITIONS | es_ES |
dc.subject | ELECTROPHILIC ALKENES | es_ES |
dc.subject | SOLID-STATE | es_ES |
dc.subject | AB-INITIO | es_ES |
dc.subject | ALDEHYDES | es_ES |
dc.subject | WATER | es_ES |
dc.subject | ACIDS | es_ES |
dc.subject | SIZE | es_ES |
dc.subject.classification | QUIMICA ORGANICA | es_ES |
dc.title | Comparison of the catalytic activity of MOFs and zeolites in Knoevenagel condensation | es_ES |
dc.type | Artículo | es_ES |
dc.identifier.doi | 10.1039/c2cy20586f | |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/FP7/228862/EU/MOFs as Catalysts and Adsorbents: Discovery and Engineering of Materials for Industrial Applications/ | |
dc.relation.projectID | info:eu-repo/grantAgreement/GACR//P106%2F12%2FG015/CZ/Intelligent design of nanoporous adsorbents and catalysts (IDENAC)/ | es_ES |
dc.rights.accessRights | Cerrado | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Departamento de Química - Departament de Química | es_ES |
dc.contributor.affiliation | Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química | es_ES |
dc.description.bibliographicCitation | Opanasenko, M.; Dhakshinamoorthy, A.; Shamzhy, M.; Nachtigall, P.; Horacek, M.; García Gómez, H.; Cejka, J. (2013). Comparison of the catalytic activity of MOFs and zeolites in Knoevenagel condensation. Catalysis Science and Technology. 3(2):500-507. https://doi.org/10.1039/c2cy20586f | es_ES |
dc.description.accrualMethod | S | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c2cy20586f | es_ES |
dc.description.upvformatpinicio | 500 | es_ES |
dc.description.upvformatpfin | 507 | es_ES |
dc.type.version | info:eu-repo/semantics/publishedVersion | es_ES |
dc.description.volume | 3 | es_ES |
dc.description.issue | 2 | es_ES |
dc.relation.senia | 242240 | es_ES |
dc.contributor.funder | Czech Science Foundation | |
dc.contributor.funder | European Commission | |
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