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Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters

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Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters

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Montesinos Magraner, M.; Vila, C.; Cantón, R.; Blay, G.; Fernández, I.; Muñoz Roca, MDC.; Pedro, JR. (2015). Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters. Angewandte Chemie International Edition. 54(21):6320-6324. doi:10.1002/anie.201501273

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/72285

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Title: Organocatalytic Asymmetric Addition of Naphthols and Electron-Rich Phenols to Isatin-Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters
Author: Montesinos Magraner, Marc Vila, Carlos Cantón, Rubén Blay, Gonzalo Fernández, Isabel Muñoz Roca, María del Carmen Pedro, José R.
UPV Unit: Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny
Issued date:
Abstract:
A quinine-derived thiourea organocatalyst promoted the highly enantioselective addition of naphthols and activated phenols to ketimines derived from isatins. The reaction afforded chiral 3-amino-2-oxindoles with a ...[+]
Subjects: Asymmetric synthesis , Friedel-Crafts reactions , Isatin-derived ketimines , Naphthols , Organocatalysis
Copyrigths: Cerrado
Source:
Angewandte Chemie International Edition. (issn: 1433-7851 ) (eissn: 1521-3773 )
DOI: 10.1002/anie.201501273
Publisher:
Wiley
Publisher version: http://dx.doi.org/10.1002/anie.201501273
Project ID:
MINECO (Gobierno de España) CTQ2013-47494-P
Generalitat Valenciana ISIC2012/001
Universitat de Valencia
MINECO
Thanks:
Financial support from the MINECO (Gobierno de Espana; CTQ2013-47494-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. M.M.-M. thanks the Universitat de Valencia for a predoctoral grant. C.V. ...[+]
Type: Artículo

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