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Influence of citric acid on the properties and stability of starch-polycaprolactone based films

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Influence of citric acid on the properties and stability of starch-polycaprolactone based films

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dc.contributor.author Ortega Toro, Rodrigo es_ES
dc.contributor.author Collazo-Bigliardi, Sofía es_ES
dc.contributor.author Talens Oliag, Pau es_ES
dc.contributor.author Chiralt, A. es_ES
dc.date.accessioned 2016-12-12T09:35:33Z
dc.date.available 2016-12-12T09:35:33Z
dc.date.issued 2015-01
dc.identifier.issn 0021-8995
dc.identifier.uri http://hdl.handle.net/10251/75105
dc.description.abstract [EN] The influence of citric acid (CA) on structural and physicochemical properties of blend films based on corn starch and polycaprolactone (PCL) was studied. Films were obtained by melt blending of starch and PCL and compression molding. Phase separation of polymers observed by scanning electron microscope and atomic force microscope was reduced by CA incorporation. CA affected both starch and PCL crystallization as deduced from the X-ray diffraction patterns and values of melting enthalpy. Glass transition of starch was reduced by PCL incorporation, while this occurred to a greater extent in films containing CA. Obtained results point to enhanced interactions between PCL and starch chains in films with CA, although this only quantitatively benefits the film properties at a low PCL ratio. Compounding starch with small amounts of PCL, using glycerol and CA, can supply films with better functional properties than net starch films. es_ES
dc.description.sponsorship The authors acknowledge the financial support from the Spanish Ministerio de Educacion y Ciencia throughout the projects AGL2010-20694 and AGL2013-42989-R. Rodrigo Ortega-Toro thanks the Conselleria de Educacio de la Comunitat Valenciana for the Santiago Grisolia grant. Authors also thank the Electron Microscopy Service of the UPV for their technical assistance. en_EN
dc.language Inglés es_ES
dc.publisher Wiley es_ES
dc.relation.ispartof Journal of Applied Polymer Science es_ES
dc.rights Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) es_ES
dc.subject Biodegradable es_ES
dc.subject Blends es_ES
dc.subject Compatibilization es_ES
dc.subject Films es_ES
dc.subject Molding es_ES
dc.subject Electron Microscopy Service of the UPV
dc.subject.classification TECNOLOGIA DE ALIMENTOS es_ES
dc.title Influence of citric acid on the properties and stability of starch-polycaprolactone based films es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/app.42220
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//AGL2010-20694/ES/FILMS Y RECUBRIMIENTOS COMESTIBLES%2FBIODEGRADABLES, CON ACTIVIDAD ANTIMICROBIANA Y ANTIOXIDANTE, PARA USO ALIMENTARIO. UTILIZACION DE PROCESADO EN HUMEDO Y EN SECO/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2013-42989-R/ES/NUEVOS MATERIALES BIODEGRADABLES MULTICAPA PARA ENVASADO ACTIVO DE ALIMENTOS SENSIBLES AL DETERIORO MICROBIANO Y%2FO OXIDATIVO/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments es_ES
dc.description.bibliographicCitation Ortega Toro, R.; Collazo-Bigliardi, S.; Talens Oliag, P.; Chiralt, A. (2015). Influence of citric acid on the properties and stability of starch-polycaprolactone based films. Journal of Applied Polymer Science. 133(2):1-16. doi:10.1002/app.42220 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://dx.doi.org/10.1002/app.42220 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 16 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 133 es_ES
dc.description.issue 2 es_ES
dc.relation.senia 290968 es_ES
dc.identifier.eissn 1097-4628
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.contributor.funder Generalitat Valenciana
dc.contributor.funder Ministerio de Economía y Competitividad
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