- -

Effect of cellulose nanocrystals on the properties of pea starch-poly(vinyl alcohol) blend films

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Effect of cellulose nanocrystals on the properties of pea starch-poly(vinyl alcohol) blend films

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Senia autor.pdf
Tamaño: 1.505Mb
Formato: PDF
Descripción: Versión del Autor.
Abrir
[Cerrado]
Nombre: Cano et al., 2015.pdf
Tamaño: 8.015Mb
Formato: PDF
Descripción: Versión editorial
Solicitar una copia al autor
dc.contributor.author Fortunati, Elena es_ES
dc.contributor.author Cano Embuena, Amalia Isabel es_ES
dc.contributor.author Cháfer Nácher, María Teresa es_ES
dc.contributor.author González Martínez, María Consuelo es_ES
dc.contributor.author Chiralt, A. es_ES
dc.contributor.author Kenny, J.M. es_ES
dc.date.accessioned 2016-12-16T08:20:36Z
dc.date.available 2016-12-16T08:20:36Z
dc.date.issued 2015-11
dc.identifier.issn 0022-2461
dc.identifier.uri http://hdl.handle.net/10251/75269
dc.description.abstract [EN] Incorporation of cellulose nanocrystals (CNC) to pea starch-poly(vinyl alcohol) (PVA) (1:2 ratio) blend films was carried out in order to improve their physical properties. Different ratios (1, 3 and 5 % wt) of CNC were used and structural, thermal and physical (barrier, mechanical and optical) properties were analysed in comparison to the control film without CNC. Incorporation of CNC enhanced phase separation of polymers in two layers. The upper PVA rich phase contained lumps of starch which emerged from the film surface, thus reducing the film gloss. CNC were dispersed in both polymeric phases as aggregates, whose size increased with the CNC ratio rise. CNC addition did not implied changes in water vapour barrier of the films, but they became slightly stiffer and more stretchable, while crystallization of PVA was partially inhibited. es_ES
dc.description.sponsorship The authors acknowledge the financial support from the Spanish Ministerio de Economia y Competitividad throughout the Projects AGL2010-20694 and AGL2013-42989-R. Amalia Cano also thanks the Spanish Ministerio de Educacion, Cultura y Deporte for the FPU grant and COST-STSM-FA1001-14253 for the financial support for the collaboration. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Microstructure es_ES
dc.subject Mechanical properties es_ES
dc.subject Nanocomposites es_ES
dc.subject Optical properties es_ES
dc.subject Phase transitions es_ES
dc.subject Water vapour permeability. es_ES
dc.subject.classification TECNOLOGIA DE ALIMENTOS es_ES
dc.title Effect of cellulose nanocrystals on the properties of pea starch-poly(vinyl alcohol) blend films es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-015-9249-9
dc.relation.projectID info:eu-repo/grantAgreement/COST//FA1001-14253/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//AGL2010-20694/ES/FILMS Y RECUBRIMIENTOS COMESTIBLES%2FBIODEGRADABLES, CON ACTIVIDAD ANTIMICROBIANA Y ANTIOXIDANTE, PARA USO ALIMENTARIO. UTILIZACION DE PROCESADO EN HUMEDO Y EN SECO./ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2013-42989-R/ES/NUEVOS MATERIALES BIODEGRADABLES MULTICAPA PARA ENVASADO ACTIVO DE ALIMENTOS SENSIBLES AL DETERIORO MICROBIANO Y%2FO OXIDATIVO/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario de Ingeniería de Alimentos para el Desarrollo - Institut Universitari d'Enginyeria d'Aliments per al Desenvolupament es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Tecnología de Alimentos - Departament de Tecnologia d'Aliments es_ES
dc.description.bibliographicCitation Fortunati, E.; Cano Embuena, AI.; Cháfer Nácher, MT.; González Martínez, MC.; Chiralt, A.; Kenny, J. (2015). Effect of cellulose nanocrystals on the properties of pea starch-poly(vinyl alcohol) blend films. Journal of Materials Science. 50(21):6979-6992. https://doi.org/10.1007/s10853-015-9249-9 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://dx.doi.org/10.1007/s10853-015-9249-9 es_ES
dc.description.upvformatpinicio 6979 es_ES
dc.description.upvformatpfin 6992 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 50 es_ES
dc.description.issue 21 es_ES
dc.relation.senia 292216 es_ES
dc.identifier.eissn 1573-4803
dc.contributor.funder Ministerio de Economía y Competitividad
dc.contributor.funder European Cooperation in Science and Technology es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte
dc.contributor.funder Ministerio de Ciencia e Innovación
dc.description.references Armentano I, Dottori M, Fortunati E, Mattioli S, Kenny JM (2010) Biodegradable polymer matrix nanocomposites for tissue engineering: a review. Polym Degrad Stab 95:2126–2146 es_ES
dc.description.references Fortunati E, Peltzer M, Armentano I, Jiménez A, Kenny JM (2013) Combined effects of cellulose nanocrystals and silver nanoparticles on the barrier and migration properties of PLA nano-biocomposites. J Food Eng 118:117–124 es_ES
dc.description.references Siracusa V, Rocculi P, Romani S, Rosa MD (2008) Biodegradable polymers for food packaging: a review. Trends Food Sci Technol 19:634–643 es_ES
dc.description.references Anandjiwala RD (2006) The role of research and development in the global competitiveness of natural fibre products, In: Natural Fibres Vision 2020 New Delhi, pp 1–15 es_ES
dc.description.references Chen Y, Liu Ch, Chang PR, Cao X, Anderson DP (2009) Bionanocomposites based on pea starch and cellulose nanowhiskers hydrolyzed from pea hull fibre: effect of hydrolysis time. Carbohydr Polym 76:607–615 es_ES
dc.description.references Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500 es_ES
dc.description.references Lee SY, Mohan DJ, Kang IE, Doh G-H, Lee S, Han SO (2009) Nanocellulose reinforced PVA composite films: effects of acid treatment and filler loading. Fibers Polym 10:77–82 es_ES
dc.description.references Zhang W, Yang X, Li C, Liang M, Lu C, Deng Y (2011) Mechanical activation of cellulose and its thermoplastic polyvinyl alcohol composites with enhanced physicochemical properties. Carbohydr Polym 83:257–263 es_ES
dc.description.references Fortunati E, Armentano I, Zhou Q, Iannoni A, Saino E, Visai L, Berglund LA, Kenny JM (2012) Multifunctional bionanocomposite films of poly(lactic acid), cellulose nanocrystals and silver nanoparticles. Carbohydr Polym 87:1596–1605 es_ES
dc.description.references Fortunati E, Puglia D, Luzi F, Santulli C, Kenny JM, Torre L (2013) Binary PVA bio-nanocomposites containing cellulose nanocrystals extracted from different natural sources: part I. Carbohydr Polym 97:825–836 es_ES
dc.description.references Cavaille JY, Ruiz MM, Dufrense A, Gerard JF, Graillat C (2000) Processing and characterization of new thermoset nanocomposites based in cellulose whiskers. Compos Interface 7(2):117–131 es_ES
dc.description.references Khoshkava V, Kamal MR (2014) Effect of drying conditions on cellulose nanocrystals (CNC) agglomerate porosity and dispersibility in polymer nanocomposites. Poweder Technol 261:288–298 es_ES
dc.description.references Sturcová A, Davies GR, Eichhorn SJ (2005) Elastic modulus and stress-transfer properties f tunicate cellulose whiskers. Biomacromolecules 6:1055–1061 es_ES
dc.description.references Fortunati E, Armentano I, Zhou Q, Puglia D, Terenzi A, Berglund LA, Kenny JM (2012) Microstructure and nanoisothermal cold crystallization of PLA composites based on silver nanoparticles and nanocrystalline cellulose. Polym Degrad Stab 97:2027–2036 es_ES
dc.description.references Rescignano N, Fortunati E, Montesano S, Emilianini C, Kenny JM, Martino S, Armentano I (2014) PVA bio-nanocomposites: a new take-off using cellulose nanocrystals and PLGA nanoparticles. Carbohydr Polym 99:47–58 es_ES
dc.description.references Siqueira G, Brasa J, Follain N, Belbekhouche S, Marais S, Dufresne A (2013) Thermal and mechanical properties of bio-nanocomposites reinforced by Luffa cylindrical cellulose nanocrystals. Carbohydr Polym 91(2):711–717 es_ES
dc.description.references Choi Y, Simonsen J (2006) Cellulose nanocrystals-filled carboxymethyl cellulose nanocomposites. J Nanosci Nanocompos 6(3):633–639 es_ES
dc.description.references Pereda M, Dufresne A, Aranguren MI, Marcovich E (2014) Polyelectrolyte films based on chitosan/olive oil and reinforced with cellulose nanocrystals. Carbohydr Polym 101:1013–1026 es_ES
dc.description.references Ma X, Chang PR, Yu J (2008) Properties of biodegradable thermoplastic pea starch/carboxymethyl cellulose and pea starch/microcrystalline cellulose composites. Carbohydr Polym 72:369–375 es_ES
dc.description.references Arrieta M, Fortunati E, Dominici F, Rayón E, Lopez J, Kenny JM (2014) PLA-PHB/cellulose based films: mechanical, barrier and disintegration properties. Carbohydr Polym 107:139–149 es_ES
dc.description.references Arrieta M, Fortunati E, Dominici F, Rayón E, Lopez J, Kenny JM (2014) Multifunctional PLA-PHB/cellulose nanocrystals films: processing, structural and thermal behavior. Carbohydr Polym 107:16–24 es_ES
dc.description.references Jiménez A, Fabra MJ, Talens P, Chiralt A (2012) Influence of hydroxypropylmethylcellulose addition and homogenization conditions on properties and ageing of corn starch based films. Carbohydr Polym 89(2):676–686 es_ES
dc.description.references Bonilla J, Atarés L, Vargas M, Chiralt A (2013) Properties of wheat starch film-forming dispersions and films as affected by chitosan addition. J Food Eng 114(3):303–312 es_ES
dc.description.references Cano A, Fortunati E, Cháfer M, Kenny JM, Chiralt A, González C (2015) Properties and ageing behavior of pea starch films as affected by blend with poly(vinyl alcohol). Food Hydrocoll 48:84–93 es_ES
dc.description.references Siddaramaiah Raj B, Somashekar R (2004) Structure–property relation in polyvinyl alcohol/starch composites. J Appl Polym Sci 9:630–635 es_ES
dc.description.references Priya B, Gupta VK, Pathania D, Singh AS (2014) Synthesis, characterization and antibacterial activity of biodegradable starch/PVA composite films reinforced with cellulosic fibre. Carbohydr Polym 109:171–179 es_ES
dc.description.references Luo X, Li J, Lin X (2012) Effect of gelatinization and additives on morphology and thermal behaviour of cornstarch/PVA blend films. Carbohydr Polym 90:1595–1600 es_ES
dc.description.references Shi R, Bi J, Zhang Z, Zhu A, Chen D, Zhou X, Zhang L, Tian W (2008) The effect of citric acid on the structural properties and cytotoxicity of the polyvinylalcohol/starch films when molding at high temperature. Carbohydr Polym 74:763–770 es_ES
dc.description.references Jiang X, Jiang T, Gan L, Zhang X, Dai H, Zhang X (2012) The plasticizing mechanism and effect of calcium chloride on starch/poly(vinyl alcohol) films. Carbohydr Polym 90:1677–1684 es_ES
dc.description.references Yoon S, Park M, Byun H (2012) Mechanical and water barrier properties of starch/PVA composite films by adding nano-sized poly(methylmethacrylate-co-acrylamide) particles. Carbohydr Polym 87:676–686 es_ES
dc.description.references Cranston ED, Gray DG (2006) Morphological and optical characterization of polyelectrolyte multilayers incorporating nanocrystalline cellulose. Biomacromolecules 7:2522–2530 es_ES
dc.description.references UNE-EN ISO (2008) Paper, board and pulps—determination of dry matter content—oven-drying method, vol 638 es_ES
dc.description.references Jiménez A, Fabra MJ, Talens P, Chiralt A (2012) Effect of re-crystallization on tensile, optical and water vapour barrier properties of corn starch films containing fatty acids. Food Hydrocoll 26:302–310 es_ES
dc.description.references Roohani M, Habibi Y, Belgacem NM, Ebrahim G, NaghiKarimi A, Dufresne A (2008) Cellulose whiskers reinforced polyvinyl alcohol copolymers nanocomposites. Eur Polym J 44:2489–2498 es_ES
dc.description.references ASTM (1995) Standard test methods for water vapour transmission of materials. Standard designations: E96-95 Annual book of ASTM standards, American Society for Testing and Materials, Philadelphia, pp 406–413 es_ES
dc.description.references Cano A, Jiménez A, Cháfer M, González C, Chiralt A (2014) Effect of amylose: amylopectin ratio and rice bran addition on starch films properties. Carbohydr Polym 111:543–555 es_ES
dc.description.references UNE-ISO 527-1 (2012) Plastics e determination of tensile properties e part 1: general principles es_ES
dc.description.references ASTM (1999) Standard test methods for specular gloss. Designation (D523). In Annual book of ASTM standards, vol 06.01. American Society for Testing and Materials, Philadelphia es_ES
dc.description.references European Standard EN 1186-1:2002 Materials and articles in contact with foodstuffs. Plastics. Guide to the selection of conditions and test methods for overall migration es_ES
dc.description.references Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food es_ES
dc.description.references Sreekumar PA, Al-Harthi MA, De SK (2012) Studies on compatibility of biodegradable starch/polyvinyl alcohol blends. Polym Eng Sci 52(10):2167–2172 es_ES
dc.description.references Chen J, Liu Ch, Chen Y, Chen Y, Chang PR (2008) Comparative study on the films of poly(vinyl alcohol)/pea starch nanocrystals and poly(vinyl alcohol)/native pea starch. Carbohydr Polym 73:8–17 es_ES
dc.description.references Jiménez A, Sánchez-González L, Desorby S, Chiralt A, Tehrany EA (2013) Influence of nanoliposomes incorporation on properties of film forming dispersions and films based on corn starch and sodium caseinate. Food Hydrocoll 35:159–169 es_ES
dc.description.references Jagadish RS, Raj B (2011) Properties and sorption studies of polyethylene oxide-starch blended films. Food Hydrocoll 25:1572–1580 es_ES
dc.description.references Fortunati E, Puglia D, Monti M, Santulli C, Maniruzzaman M, Kenny JM (2013) Cellulose nanocrystals extracted from Okra Fibers in PVA nanocomposites. J Appl Polym Sci 128:3220–3230. doi: 10.1002/APP.38524 es_ES
dc.description.references Abdelrazek EM, Elashmawi IS, Labeeb S (2010) Chitosan filler effects on the experimental characterization, spectroscopic investigation and thermal studies of PVA/PVP blend films. Phys B 405:2021–2027 es_ES
dc.description.references Peresin MS, Habibi Y, Zoppe JO, Pawlak JJ, Rojas OJ (2010) Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: manufacture and characterization. Biomacromolecules 11(3):674–681 es_ES
dc.description.references Favier V, Cavaillé JY, Canova GR, Shrivastavas SC (1997) Mechanical percolation in cellulose whisker nanocomposites. Polym Eng Sci 37(10):1732–1739 es_ES
dc.description.references Schmidt B, Katiyar V, Plackett D, Larsen EH, Gerds N, Bender Koch C (2011) Migration of nanosized layered double hydroxide platelets from polylactide nanocomposite films. Food Addit Contam 28:956–966 es_ES
dc.description.references Fortunati E, Peltzer M, Armentano I, Torre L, Jiménez A, Kenny JM (2012) Effects of modified cellulose nanocrystals on the barrier and migration properties of PLA nano-biocomposites. Carbohydr Polym 90:948–956 es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem