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Diels-Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels-Alder reaction

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Diels-Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels-Alder reaction

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dc.contributor.author Cantin Sanz, Angel es_ES
dc.contributor.author Gomez, M. Victoria es_ES
dc.contributor.author de la Hoz, Antonio es_ES
dc.date.accessioned 2017-05-23T10:00:33Z
dc.date.available 2017-05-23T10:00:33Z
dc.date.issued 2016-10-13
dc.identifier.issn 1860-5397
dc.identifier.uri http://hdl.handle.net/10251/81647
dc.description.abstract Diels-Alder cycloaddition between cyclopentadiene and p-benzoquinone has been studied in the confined space of a pure silica zeolite Beta and the impact on reaction rate due to the concentration effect within the pore and diffusion limitations are discussed. Introduction of Lewis or Bronsted acid sites on the walls of the zeolite strongly increases the reaction rate. However, contrary to what occurs with mesoporous molecular sieves (MCM-41), Beta zeolite does not catalyse the retro-Diels-Alder reaction, resulting in a highly selective catalyst for the cycloaddition reaction. es_ES
dc.description.sponsorship Financial support from the Ministerio de Economia y Competitividad through projects MAT2015-71261-R and CTQ2014-54987-P, are greatly acknowledged. M. V. Gomez thanks MINECO for participation in the Ramon y Cajal program. The authors thank M. Moliner, M. T. Navarro, S. Valencia for providing all the catalytic materials used in this study. en_EN
dc.language Inglés es_ES
dc.publisher Beilstein-Institut es_ES
dc.relation.ispartof Beilstein Journal of Organic Chemistry es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Catalysis,Diels-Alder,retro-Diels-Alder,zeolites es_ES
dc.subject Catalysis es_ES
dc.subject Diels-Alder es_ES
dc.subject Retro-Diels-Alder es_ES
dc.subject Zeolites es_ES
dc.title Diels-Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels-Alder reaction es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3762/bjoc.12.208
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2015-71261-R/ES/DISEÑO RACIONAL DE MATERIALES ZEOLITICOS CON CENTROS METALICOS PARA SU APLICACION EN PROCESOS QUIMICOS SOSTENIBLES, MEDIOAMBIENTALES Y ENERGIAS RENOVABLES/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-54987-P/ES/MICROBOBINAS DE RMN EN EL DESARROLLO DE NUEVAS METODOLOGIAS DE POLARIZACION NUCLEAR DINAMICA QUIMICAMENTE INDUCIDA (PHOTO-CIDNP)/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Cantin Sanz, A.; Gomez, MV.; De La Hoz, A. (2016). Diels-Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels-Alder reaction. Beilstein Journal of Organic Chemistry. 12:2181-2188. https://doi.org/10.3762/bjoc.12.208 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.3762/bjoc.12.208 es_ES
dc.description.upvformatpinicio 2181 es_ES
dc.description.upvformatpfin 2188 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.relation.senia 331946 es_ES
dc.identifier.pmid 27829925 en_EN
dc.identifier.pmcid PMC5082480 en_EN


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