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Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy

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Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy

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Oliver-Tomás, B.; Gonell-Gómez, F.; Pulido, A.; Renz, M.; Boronat Zaragoza, M. (2016). Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy. Catalysis Science and Technology. 6(14):5561-5566. doi:10.1039/c6cy00395h

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/81820

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Title: Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy
Author:
UPV Unit: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
[EN] The kinetics of the ketonic decarboxylation of linear and branched carboxylic acids over m-ZrO2 as a catalyst has been investigated. The same apparent activation energy is experimentally determined for the ketonic ...[+]
Subjects: Catalytic ketonization , Acetic-acid , Chemical , Biomass , Condensation , Mechanism , Zirconia , Oxides , Fuels
Copyrigths: Reserva de todos los derechos
Source:
Catalysis Science and Technology. (issn: 2044-4753 ) (eissn: 2044-4761 )
DOI: 10.1039/c6cy00395h
Publisher:
Royal Society of Chemistry
Publisher version: http://dx.doi.org/10.1039/c6cy00395h
Thanks:
The authors thank MINECO (Consolider Ingenio 2010-MULTICAT, CSD2009-00050 and Severo Ochoa program, SEV-2012-0267), Generalitat Valenciana (PROMETEOII/2013/011 Project), and the Spanish National Research Council (CSIC, Es ...[+]
Type: Artículo

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