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Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy

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Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy

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Oliver-Tomás, B.; Gonell-Gómez, F.; Pulido, A.; Renz, M.; Boronat Zaragoza, M. (2016). Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy. Catalysis Science and Technology. 6(14):5561-5566. https://doi.org/10.1039/c6cy00395h

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Título: Effect of the C-alpha substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO2: the role of entropy
Autor: Oliver-Tomás, Borja Gonell-Gómez, Francisco Pulido, Angeles Renz, Michael Boronat Zaragoza, Mercedes
Entidad UPV: Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
[EN] The kinetics of the ketonic decarboxylation of linear and branched carboxylic acids over m-ZrO2 as a catalyst has been investigated. The same apparent activation energy is experimentally determined for the ketonic ...[+]
Palabras clave: Catalytic ketonization , Acetic-acid , Chemical , Biomass , Condensation , Mechanism , Zirconia , Oxides , Fuels
Derechos de uso: Reserva de todos los derechos
Fuente:
Catalysis Science and Technology. (issn: 2044-4753 ) (eissn: 2044-4761 )
DOI: 10.1039/c6cy00395h
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/c6cy00395h
Código del Proyecto:
info:eu-repo/grantAgreement/MICINN//CSD2009-00050/ES/Desarrollo de catalizadores más eficientes para el diseño de procesos químicos sostenibles y produccion limpia de energia/
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/GVA//PROMETEOII%2F2013%2F011/ES/Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas (PROMETEO)/
info:eu-repo/grantAgreement/CSIC//2010RU0108/
Agradecimientos:
The authors thank MINECO (Consolider Ingenio 2010-MULTICAT, CSD2009-00050 and Severo Ochoa program, SEV-2012-0267), Generalitat Valenciana (PROMETEOII/2013/011 Project), and the Spanish National Research Council (CSIC, Es ...[+]
Tipo: Artículo

References

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