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Characterization of Crosslinked Poly(vinyl alcohol)-Based Membranes with Different Hydrolysis Degrees for Their Use as Electrolytes in Direct Methanol Fuel Cells

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Characterization of Crosslinked Poly(vinyl alcohol)-Based Membranes with Different Hydrolysis Degrees for Their Use as Electrolytes in Direct Methanol Fuel Cells

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Martinez-Felipe, A.; Moliner Estopiñán, CE.; Imrie, CT.; Ribes Greus, MD. (2012). Characterization of Crosslinked Poly(vinyl alcohol)-Based Membranes with Different Hydrolysis Degrees for Their Use as Electrolytes in Direct Methanol Fuel Cells. Journal of Applied Polymer Science. 124:1000-1011. doi:10.1002/app.35138.

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Título: Characterization of Crosslinked Poly(vinyl alcohol)-Based Membranes with Different Hydrolysis Degrees for Their Use as Electrolytes in Direct Methanol Fuel Cells
Autor:
Entidad UPV: Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials
Universitat Politècnica de València. Escuela Técnica Superior de Ingeniería del Diseño - Escola Tècnica Superior d'Enginyeria del Disseny
Fecha difusión:
Resumen:
The effect of the degree of hydrolysis of poly(vinyl alcohol) (PVA) substrates on the preparation and properties of crosslinked membranes prepared via esterification with sulfosuccinic acid (SSA) has been studied using ...[+]
Palabras clave: Crosslinking , FTIR , Polymer synthesis and characterization , Renewable resources , Thermogravimetric analysis (TGA) , ATR FTIR , Bound waters , Cross linked membranes , Crosslinked , Crosslinked structures , Degree of hydrolysis , FTIR spectroscopy , High temperature , Higher-degree , Hydrolysis degree , Ionic exchange , Methanol selectivity , Preparation and properties , Renewable resource , Swelling test , Direct methanol fuel cells (DMFC) , Electrolytes , Esterification , Esters , Fourier transform infrared spectroscopy , Heat treatment , Hydrolysis , Ion exchange , Membranes , Methanol , Methanol fuels , Polyvinyl alcohols , Spectroscopy , Substrates , Thermodynamic stability , Thermogravimetric analysis
Derechos de uso: Cerrado
Fuente:
Journal of Applied Polymer Science. (issn: 0021-8995 )
DOI: 10.1002/app.35138
Editorial:
Wiley
Versión del editor: http://dx.doi.org/10.1002/app.35138
Patrocinador:
Spanish Ministry of Science and Innovation grant IT2009-0074
Spanish Ministry of Science and Innovation grant UPOVCE-3E-013
Spanish Ministry of Science and Innovation grant ENE2007-67584-C03
UPOVCE-3E-013
Generalitat Valenciana; contract grant number: Grisolia and Forteza 2010 and 2011
Tipo: Artículo

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