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Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption

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Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption

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dc.contributor.author Pera-Titus, Marc es_ES
dc.contributor.author Palomino Roca, Miguel es_ES
dc.contributor.author Valencia Valencia, Susana es_ES
dc.contributor.author Rey Garcia, Fernando es_ES
dc.date.accessioned 2017-07-17T10:48:09Z
dc.date.available 2017-07-17T10:48:09Z
dc.date.issued 2014
dc.identifier.issn 1463-9076
dc.identifier.uri http://hdl.handle.net/10251/85254
dc.description.abstract [EN] Fully dehydrated and partially sodium-cesium containing RHO zeolite (Na,Cs-RHO) shows a genuine inflection in the CO2 isotherms in the temperature range 293-333 K that can be attributed to a sorbate-induced framework deformation from an acentric (A) to a centric (C) phase due to a partial cation rearrangement. This peculiar sorption pattern can be captured by the formulation of thermodynamic isotherms, providing a direct enthalpic and entropic signature of the CO2 adsorption-desorption process during deformation. Using this formulation, the energy barrier between the acentric and centric phases for CO2 adsorption-desorption was estimated in the range 4.7-9.6 J g(-1) of solid (15-32 kJ mol(-1)), reflecting a higher CO2 affinity for the acentric phase, whereas the elastic energy involved during framework distortion was estimated in the range 6-12 J g(-1) of solid (19-39 kJ mol(-1)) with a relative maximum at 303 K and showing a dominant entropic contribution. es_ES
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation.ispartof Physical Chemistry Chemical Physics es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject RHO zeolite es_ES
dc.subject CO2 adsorption es_ES
dc.subject Thermodynamic isotherms es_ES
dc.subject Phase transformation es_ES
dc.subject Zeolite es_ES
dc.subject Adsorption es_ES
dc.title Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/C4CP03409K
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Pera-Titus, M.; Palomino Roca, M.; Valencia Valencia, S.; Rey Garcia, F. (2014). Thermodynamic analysis of framework deformation in Na,Cs-RHO zeolite upon CO2 adsorption. Physical Chemistry Chemical Physics. 16(44):24391-24400. doi:10.1039/C4CP03409K es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1039/c4cp03409k es_ES
dc.description.upvformatpinicio 24391 es_ES
dc.description.upvformatpfin 24400 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 16 es_ES
dc.description.issue 44 es_ES
dc.relation.senia 276454 es_ES
dc.identifier.eissn 1463-9084
dc.identifier.pmid 25300941
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