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BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP

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BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP

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dc.contributor.author Gotor Candel, Raul Jesús es_ES
dc.contributor.author Gaviña Costero, Pablo es_ES
dc.contributor.author Ochando Gómez, Luis Enrique es_ES
dc.contributor.author Chulvi, Katherine es_ES
dc.contributor.author Lorente, Alejandro es_ES
dc.contributor.author Martínez-Máñez, Ramón es_ES
dc.contributor.author Costero, Ana M. es_ES
dc.date.accessioned 2018-01-11T10:14:01Z
dc.date.available 2018-01-11T10:14:01Z
dc.date.issued 2014 es_ES
dc.identifier.uri http://hdl.handle.net/10251/94484
dc.description.abstract [EN] Two OFF-ON fluorescent chemodosimeters based on a BODIPY core for the detection of nerve agent mimics have been synthesized. Their reactivity towards diethylcyanophosphonate (DCNP) and diisopropylfluorophosphate (DFP) has been tested in organic and aqueous phase. These chemodosimeters selectively detect the nerve agent mimics with good LODs. The chemodosimeters hold their sensing properties on solid supports, allowing the preparation of a hand held sensing kit. The sensing in solid-liquid phase has been demonstrated. The X-ray structure of compound 2 has been resolved. es_ES
dc.description.sponsorship We thank the Spanish Government and the European FEDER funds (project MAT2012-38429-C04-02 and 01). SCSIE and ICMOL (Universidad de Valencia) are gratefully acknowledged for all the equipment employed. R.G. is grateful to the Spanish Ministry of Education for its FPU grant. Dr Knut Rurack is gratefully acknowledged for instrumental support and fruitful discussion.
dc.language Inglés es_ES
dc.publisher The Royal Society of Chemistry es_ES
dc.relation MINECO/MAT2012-38429-C04-01 es_ES
dc.relation.ispartof RSC Advances es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Biological Warfare Agents es_ES
dc.subject Organophosphorus Hydrolase es_ES
dc.subject Optical-Properties es_ES
dc.subject Spectroscopic Properties es_ES
dc.subject Electrochemical Sensor es_ES
dc.subject Photonic Crystal es_ES
dc.subject Dmmp Detection es_ES
dc.subject Derivatives es_ES
dc.subject Biosensor es_ES
dc.subject Acetylcholinesterase es_ES
dc.subject.classification QUIMICA INORGANICA es_ES
dc.title BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c4ra00710g es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico - Institut de Reconeixement Molecular i Desenvolupament Tecnològic es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gotor Candel, RJ.; Gaviña Costero, P.; Ochando Gómez, LE.; Chulvi, K.; Lorente, A.; Martínez-Máñez, R.; Costero, AM. (2014). BODIPY dyes functionalized with 2-(2-dimethylaminophenyl) ethanol moieties as selective OFF-ON fluorescent chemodosimeters for the nerve agent mimics DCNP and DFP. RSC Advances. 4(31):15975-15982. doi:10.1039/c4ra00710g es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1039/c4ra00710g es_ES
dc.description.upvformatpinicio 15975 es_ES
dc.description.upvformatpfin 15982 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 4 es_ES
dc.description.issue 31 es_ES
dc.identifier.eissn 2046-2069 es_ES
dc.relation.pasarela 278807 es_ES
dc.contributor.funder Ministerio de Economía, Industria y Competitividad (MINECO) es_ES


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