Amarajothi, Dhakshinamoorthy; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Royal Society of Chemistry, 2012)
Metal¿organic frameworks (MOFs) are porous crystalline materials that have promising
applications as heterogeneous catalysts. After describing the composition, textural properties and
crystal structure of four commercially ...
Amarajothi, Dhakshina Moorthy; Alvaro Rodríguez, Maria Mercedes; Horcajada Campos, Patricia; Gibson, Emma; Vishnuvarthan, Muthusamy; Vimont, Alexandre; Grenèche, Jean-Marc; Serre, Christian; Daturi, Marco; García Gómez, Hermenegildo(American Chemical Society, 2012-08)
[EN] Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL stands for Material of Institut Lavoisier) of welldefined ...
Espinosa-López, Juan Carlos; Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2016)
[EN] A series of catalysts consisting of Cu nanoparticles (NPs) supported on diamond nanoparticles (D) were obtained by polyol reduction of CuNO3)(2) in the presence of D. The best performing Cu/D catalyst was obtained ...
Blandez Barradas, Juan Francisco; Primo Arnau, Ana María; Asiri, Abdullah; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley-VCH Verlag, 2014-11-10)
[EN] Copper nanoparticles (NPs) supported on a series of
undoped and doped graphene materials (Gs) have been
obtained by pyrolysis of alginate or chitosan biopolymers,
modified or not with boric acid, containing Cu2+ ...
[EN] MIL-125(Ti)-NH2 has been modified by reaction of salicylaldehyde with the terephthalate amino groups to form a salicylideneimine that act as ligand of Cu2+. The success of the postsynthetic modification was assessed ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Springer Verlag, 2015-08)
[EN] Cu-3(BTC)(2) deactivates by deterioration of its crystal structure during the use of this metal organic framework as catalyst in the synthesis of 2-phenylquinoxaline from phenacylbromide and o-phenylenediamine at room ...
Dhakshinamoorthy, Amarajothi; Alvaro Rodríguez, Maria Mercedes; Corma Canós, Avelino; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2011)
[EN] This perspective article is aimed at providing a comparison of similarities and dissimilarities between the catalytic properties of zeolites and metal organic frameworks (MOFs). In the first part of the paper, we ...
Vallés-García, Cristina; Gkaniatsou, Effrosyni; Santiago-Portillo, Andrea; Giménez-Marqués, Mónica; Alvaro Rodríguez, Maria Mercedes; Greneche, Jean-Marc; Steunou, Nathalie; Sicard, Clemence; Navalón Oltra, Sergio; Serre, Christian; García Gómez, Hermenegildo(The Royal Society of Chemistry, 2020-09-07)
[EN] This work highlights the benefit of designing mixed-metal (Cr/Fe) MOFs for enhanced chemical stability and catalytic activity. A robust and stable mixed-metal MIL-101(Cr/Fe) was prepared through a HF-free direct ...
Serra, Marco; García Baldoví, Hermenegildo; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley, 2015-09)
[EN] In the search for novel photocatalysts for hydrogen production and with the alpha-Fe2O3 photoelectrocatalyst as a recent precedent, we report herein the preparation, semiconductor properties and photocatalytic activity ...
DHAKSHINAMOORTHY, AMARAJOTHI; Primo Arnau, Ana María; Concepción Heydorn, Patricia; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Wiley, 2013-06)
[EN] Nitrogen (N)-, boron (B)-, and boron,nitrogen (B,N)-doped graphene (G) act as carbocatalysts, promoting the aerobic oxidation of the benzylic positions of aromatic hydrocarbons and cyclooctane to the corresponding ...
Aprile, Carmela; Teruel Biosca, Laura; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(NRC Research Press (Canadian Science Publishing), 2011-02)
Using cetyltrimethylammonium bromide as the structure-directing agent, titania nanoparticles (3–5 nm) were organized
into a mesoporous material (8.6 nm average pore size and 99 m2/g). The textural and spatial structuring ...
Manickam-Periyaraman, Premkumar; Espinosa, Sergio Manuel; Espinosa-López, Juan Carlos; Navalón Oltra, Sergio; Subramanian, Sivanesan; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo(Elsevier, 2016)
[EN] Herein we report that silver nanoparticles supported on commercial diamond nanoparticles functionalized with hydroxyl groups (D3) is a cost-effective heterogeneous catalyst for the decolorization of different synthetic ...
Navalón Oltra, Sergio; Alvaro Rodríguez, Maria Mercedes; Dhakshinamoorthy, Amarajothi; García Gómez, Hermenegildo(MDPI AG, 2019-09-01)
[EN] Nitro group reduction is a reaction of a considerable importance for the preparation of bulk chemicals and in organic synthesis. There are reports in the literature showing that incorporation of metal nanoparticles ...
Espinosa-López, Juan Carlos; Alvaro Rodríguez, Maria Mercedes; Dhakshinamoorthy, Amarajothi; Navalón Oltra, Sergio; García Gómez, Hermenegildo(American Chemical Society, 2019-10-07)
[EN] The influence of the graphene oxide (GO) reduction method on the activity of the resulting reduced graphene oxide (rGO) for the aerobic oxidation of benzylamine is reported. Starting from GO obtained by the Hummers ...
Vallés García, Cristina(Universitat Politècnica de València, 2021-10-28)
[ES] La presente tesis doctoral ha mostrado la posibilidad de diseñar sitios activos de MOFs y materiales basados en grafeno para ser utilizados como catalizadores con actividad mejorada para reacciones de oxidación y ...
Espinosa-López, Juan Carlos; Manickam-Periyaraman, Premkumar; Bernat-Quesada, Francisco; Sivanesan, Subramanian; Alvaro Rodríguez, Maria Mercedes; García Gómez, Hermenegildo; Navalón Oltra, Sergio(Elsevier, 2019-07-15)
[EN] Commercial activated carbon has been functionalized by chemical or thermal treatments to introduce surface oxygen functional groups able to anchor small cobalt nanoparticles with superior catalytic activity for ...