[EN] Understanding and tuning the catalytic properties of metals atomically dispersed on oxides are major stepping-stones toward a rational development of single-atom catalysts (SACs). Beyond individual showcase studies, ...
[EN] The present numerical study concerns the dispersion and deposition of a nasal spray in a patient-specific human
nose. The realistic three-dimensional geometry of the nasal cavity is reconstructed from computer ...
[EN] Realizing the full potential of oxide-supported single-atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one-pot ...
Liu, Ying-Ya; Grzywa, Maciej; Tonigold, Markus; Sastre Navarro, German Ignacio; Schuettrigkeit, Tanja; Leeson, Nicholas S.; Volkmer, Dirk(Royal Society of Chemistry, 2011)
The syntheses of Kuratowski-type pentanuclear clusters featuring {MZn4Cl4} cores (M-II = Ru or Zn) that incorporate triazolate ligands are described. The coordination compounds are characterized by single-crystal X-ray ...
[EN] The potential of oxide-supported rhodium single atom catalysts (SACs) for heterogeneous hydroformylation was investigated both theoretically and experimentally. Using high-level domain-based local-pair natural orbital ...
[EN] A frontier challenge in single-atom (SA) catalysis is the design of fully inorganic sites capable of emulating the high reaction selectivity traditionally exclusive of organometallic counterparts in homogeneous ...