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Optimization of Maleinized Linseed Oil Loading as a Biobased Compatibilizer in Poly(Butylene Succinate) Composites with Almond Shell Flour

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Optimization of Maleinized Linseed Oil Loading as a Biobased Compatibilizer in Poly(Butylene Succinate) Composites with Almond Shell Flour

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dc.contributor.author Limiñana-Gregori, Patricia es_ES
dc.contributor.author Garcia-Sanoguera, David es_ES
dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.date.accessioned 2020-02-19T21:00:37Z
dc.date.available 2020-02-19T21:00:37Z
dc.date.issued 2019 es_ES
dc.identifier.uri http://hdl.handle.net/10251/137339
dc.description.abstract [EN] Green composites of poly(butylene succinate) (PBS) were manufactured with almond shell flour (ASF) by reactive compatibilization with maleinized linseed oil *MLO) by extrusion and subsequent injection molding. ASF was kept constant at 30 wt %, while the effect of different MLO loading on mechanical, thermal, thermomechanical, and morphology properties was studied. Uncompatibilized PBS/ASF composites show a remarkable decrease in mechanical properties due to the nonexistent polymer¿filler interaction, as evidenced by field emission scanning electron microscopy (FESEM). MLO provides a plasticization effect on PBS/ASF composites but, in addition, acts as a compatibilizer agent since the maleic anhydride groups contained in MLO are likely to react with hydroxyl groups in both PBS end chains and ASF particles. This compatibilizing effect is observed by FESEM with a reduction of the gap between the filler particles and the surrounding PBS matrix. In addition, the Tg of PBS increases from ¿28 °C to ¿12 °C with an MLO content of 10 wt %, thus indicating compatibilization. MLO has been validated as an environmentally friendly additive to PBS/ASF composites to give materials with high environmental efficiency. es_ES
dc.description.sponsorship This work was supported by the Ministry of Economy and Competitiveness (MINECO) grant number MAT2017-84909-C2-2-R. L.Q.-C. wants to thank Generalitat Valenciana (GV) for his FPI grant (ACIF/2016/182) and the Spanish Ministry of Education, Culture, and Sports (MECD) for his FPU grant (FPU15/03812). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Materials es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Polymer-matrix composites (PMCs) es_ES
dc.subject Mechanical properties es_ES
dc.subject Thermomechanical es_ES
dc.subject Electron microscopy es_ES
dc.subject Compatibilizers es_ES
dc.subject.classification INGENIERIA MECANICA es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title Optimization of Maleinized Linseed Oil Loading as a Biobased Compatibilizer in Poly(Butylene Succinate) Composites with Almond Shell Flour es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/ma12050685 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84909-C2-2-R/ES/PROCESADO Y OPTIMIZACION DE MATERIALES AVANZADOS DERIVADOS DE ESTRUCTURAS PROTEICAS Y COMPONENTES LIGNOCELULOSICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//ACIF%2F2016%2F182/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Limiñana-Gregori, P.; Garcia-Sanoguera, D.; Quiles-Carrillo, L.; Balart, R.; Montanes, N. (2019). Optimization of Maleinized Linseed Oil Loading as a Biobased Compatibilizer in Poly(Butylene Succinate) Composites with Almond Shell Flour. Materials. 12(5):1-14. https://doi.org/10.3390/ma12050685 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/ma12050685 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 14 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 12 es_ES
dc.description.issue 5 es_ES
dc.identifier.eissn 1996-1944 es_ES
dc.relation.pasarela S\379177 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
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