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Air-Stable, Dinuclear and Tetranuclear sigma,pi-Acetylide Gold(I) Complexes and Their Catalytic Implications

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Air-Stable, Dinuclear and Tetranuclear sigma,pi-Acetylide Gold(I) Complexes and Their Catalytic Implications

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dc.contributor.author Grirrane, Abdessamad es_ES
dc.contributor.author García Gómez, Hermenegildo es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.contributor.author Alvarez González, Eleuterio es_ES
dc.date.accessioned 2020-04-06T08:55:34Z
dc.date.available 2020-04-06T08:55:34Z
dc.date.issued 2013 es_ES
dc.identifier.issn 0947-6539 es_ES
dc.identifier.uri http://hdl.handle.net/10251/140182
dc.description.abstract [EN] Two for one gold: Factors governing the formation of isolable digold(I) ó,ð-acetylide complexes are given (see scheme), indicating the general tendency of phosphine AuI precatalysts to form this type of complexes, which are involved as reaction intermediates in gold(I)-catalyzed reactions. Mechanistic insights into the intermolecular hydroamination of aniline and terminal alkynes catalyzed by gold(I) have shown the role of a fluxional, cationic ó,ð-digold alkynide complex as one of the intermediates in the formation of imines. es_ES
dc.description.sponsorship Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and CTQ2012-36351) and Generalidad Valenciana (Prometeo 2012/014) is gratefully acknowledged es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Chemistry - A European Journal es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Gold es_ES
dc.subject Gold complexes es_ES
dc.subject Gold nanoparticles es_ES
dc.subject Homogeneous catalysis es_ES
dc.subject Hydroamination reactions es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.title Air-Stable, Dinuclear and Tetranuclear sigma,pi-Acetylide Gold(I) Complexes and Their Catalytic Implications es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/chem.201301623 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/GVA//PROMETEO%2F2012%2F014/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2012-32315/ES/REDUCCION FOTOCATALITICA DEL DIOXIDO DE CARBONO/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Grirrane, A.; García Gómez, H.; Corma Canós, A.; Alvarez González, E. (2013). Air-Stable, Dinuclear and Tetranuclear sigma,pi-Acetylide Gold(I) Complexes and Their Catalytic Implications. Chemistry - A European Journal. 19(37):12239-12244. https://doi.org/10.1002/chem.201301623 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/chem.201301623 es_ES
dc.description.upvformatpinicio 12239 es_ES
dc.description.upvformatpfin 12244 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 19 es_ES
dc.description.issue 37 es_ES
dc.relation.pasarela S\256264 es_ES
dc.contributor.funder Generalitat Valenciana es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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