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On the use of acrylated epoxidized soybean oil as a reactive compatibilizer in injection-molded compostable pieces consisting of polylactide filled with orange peel flour

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On the use of acrylated epoxidized soybean oil as a reactive compatibilizer in injection-molded compostable pieces consisting of polylactide filled with orange peel flour

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dc.contributor.author Quiles-Carrillo, Luis es_ES
dc.contributor.author Montanes, Nestor es_ES
dc.contributor.author Lagaron, Jose Maria es_ES
dc.contributor.author Balart, Rafael es_ES
dc.contributor.author Torres-Giner, Sergio es_ES
dc.date.accessioned 2020-04-22T08:01:26Z
dc.date.available 2020-04-22T08:01:26Z
dc.date.issued 2018-10 es_ES
dc.identifier.issn 0959-8103 es_ES
dc.identifier.uri http://hdl.handle.net/10251/141302
dc.description.abstract [EN] In the present study, novel green composites made of polylactide (PLA) and orange peel flour (OPF) were melt compounded by twin¿screw extrusion (TSE) and shaped into pieces by injection molding. Orange peel, a large by¿product of the juice industry, was first grounded to flour and then incorporated as a lignocellulosic filler into the biopolymer at 10, 20, and 30 wt.¿%. Since both components of the green composite presented low compatibility, the resultant injection¿molded pieces showed poor ductility and impaired thermomechanical performance. As a new bio¿based reactive compatibilizer, acrylated epoxidized soybean oil (AESO) was added at 5 parts per hundred resin (phr) to the PLA/OPF formulations during the extrusion process. The addition of AESO increased the filler¿biopolymer adhesion and led to compostable green composite pieces with improved physical properties. The enhancement achieved was related to a dual effect of plasticization and melt grafting of the OPF particles onto the PLA chains provided by the multiple acrylate and epoxy groups present in AESO. The use of multi¿functionalized vegetable oils to improve the performance of green composites certainly opens up new opportunities for the expansion of fully bio¿based and biodegradable materials that are partially obtained from agro¿food waste. es_ES
dc.description.sponsorship This research was supported by the Spanish Ministry of Economy and Competitiveness (MINECO) program numbers MAT2014-59242-C2-1-R and AGL2015-63855-C2-1-R. LQ-C also thanks the Spanish Ministry of Education, Culture, and Sports (MECD) for financial support through FPU grant number FPU15/03812. es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof Polymer International es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject PLA es_ES
dc.subject Green composites es_ES
dc.subject Multi-functionalized vegetable oils es_ES
dc.subject Reactive extrusion es_ES
dc.subject Waste valorization es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.title On the use of acrylated epoxidized soybean oil as a reactive compatibilizer in injection-molded compostable pieces consisting of polylactide filled with orange peel flour es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/pi.5588 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//MAT2014-59242-C2-1-R/ES/TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//AGL2015-63855-C2-1-R/ES/DESARROLLO DE UN CONCEPTO DE ENVASE MULTICAPA ALIMENTARIO DE ALTA BARRERA Y CON CARACTER ACTIVO Y BIOACTIVO DERIVADO DE SUBPRODUCTOS ALIMENTARIOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU15%2F03812/ES/FPU15%2F03812/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//IJCI-2016-29675/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Quiles-Carrillo, L.; Montanes, N.; Lagaron, JM.; Balart, R.; Torres-Giner, S. (2018). On the use of acrylated epoxidized soybean oil as a reactive compatibilizer in injection-molded compostable pieces consisting of polylactide filled with orange peel flour. Polymer International. 67(10):1341-1351. https://doi.org/10.1002/pi.5588 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/pi.5588 es_ES
dc.description.upvformatpinicio 1341 es_ES
dc.description.upvformatpfin 1351 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 67 es_ES
dc.description.issue 10 es_ES
dc.relation.pasarela S\360876 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
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