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Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives

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Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives

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dc.contributor.author Gutiérrez-Tarriño, Silvia es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author Oña-Burgos, Pascual es_ES
dc.date.accessioned 2020-06-04T06:30:29Z
dc.date.available 2020-06-04T06:30:29Z
dc.date.issued 2018-12-06 es_ES
dc.identifier.issn 1434-1948 es_ES
dc.identifier.uri http://hdl.handle.net/10251/145196
dc.description.abstract [EN] Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. Here, we report a simple method for the use of air-stable cobalt catalysts for anti-Markovnikov alkene hydrosilylation that can be used under aerobic conditions without dry solvents or additives. These catalysts can be generated from low-cost commercially available materials. In addition, these catalysts possess good catalytic ability for both hydrosilanes and hydroalkoxysilanes. Finally, a mechanistic study demonstrates that the silane and the catalyst generate a Co-H species in the course of the reaction, which has been observed by in situ Raman spectroscopy. es_ES
dc.description.sponsorship Program Severo Ochoa SEV-2016-0683 is gratefully acknowledged. S. G. T. and P. O.-B. thank MINECO for a FPU Ph.D. fellowship FPU16/02117 and a Ramon y Cajal contract RYC-2014-16620, respectively. Authors would like to thank Prof. Avelino Corma for discussion on the work and support. Authors would like to thank Ms. Adelina Munoz, Dr. Alejandro Vidal, and Ms. Carmen Clemente for the Raman, EPR, and ESI-MS measurements, respectively. Authors are also grateful for the use of analytical facilities at the X-ray Unit of RIAIDT (Universidad de Santiago de Compostela). es_ES
dc.language Inglés es_ES
dc.publisher John Wiley & Sons es_ES
dc.relation.ispartof European Journal of Inorganic Chemistry es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Homogeneous catalysis es_ES
dc.subject Cobalt es_ES
dc.subject Alkenes es_ES
dc.subject Hydrosilylation es_ES
dc.subject Reaction mechanisms es_ES
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1002/ejic.201801068 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MECD//FPU16%2F02117/ES/FPU16%2F02117/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//RYC-2014-16620/ES/RYC-2014-16620/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Gutiérrez-Tarriño, S.; Concepción Heydorn, P.; Oña-Burgos, P. (2018). Cobalt Catalysts for Alkene Hydrosilylation under Aerobic Conditions without Dry Solvents or Additives. European Journal of Inorganic Chemistry. 45:4867-4874. https://doi.org/10.1002/ejic.201801068 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1002/ejic.201801068 es_ES
dc.description.upvformatpinicio 4867 es_ES
dc.description.upvformatpfin 4874 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 45 es_ES
dc.relation.pasarela S\373666 es_ES
dc.contributor.funder Ministerio de Educación, Cultura y Deporte es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
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