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Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance

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Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance

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dc.contributor.author Cucciniello, Raffaele es_ES
dc.contributor.author Intiso, Adriano es_ES
dc.contributor.author Siciliano, Tiziana es_ES
dc.contributor.author Palomares Gimeno, Antonio Eduardo es_ES
dc.contributor.author Martínez-Triguero, Joaquín es_ES
dc.contributor.author Cerrillo, José Luis es_ES
dc.contributor.author Proto, Antonio es_ES
dc.contributor.author Rossi, Federico es_ES
dc.date.accessioned 2020-11-17T04:32:16Z
dc.date.available 2020-11-17T04:32:16Z
dc.date.issued 2019-09-05 es_ES
dc.identifier.uri http://hdl.handle.net/10251/155121
dc.description.abstract [EN] Mayenite was recently successfully employed as an active catalyst for trichloroethylene (TCE) oxidation. It was effective in promoting the conversion of TCE in less harmful products (CO2 and HCl) with high activity and selectivity. However, there is a potential limitation to the use of mayenite in the industrial degradation of chlorinated compounds-its limited operating lifespan owing to chlorine poisoning of the catalyst. To overcome this problem, in this work, mayenite-based catalysts loaded with iron (Fe/mayenite) were prepared and tested for TCE oxidation in a gaseous phase. The catalysts were characterized using different physico-chemical techniques, including XRD, ICP, N-2-sorption (BET), H-2-TPR analysis, SEM-EDX, XPS FESEM-EDS, and Raman. Fe/mayenite was found to be more active and stable than the pure material for TCE oxidation, maintaining the same selectivity. This result was interpreted as the synergistic effect of the metal and the oxo-anionic species present in the mayenite framework, thus promoting TCE oxidation, while avoiding catalyst deactivation. es_ES
dc.description.sponsorship This work was supported by the grants ORSA167988 and ORSA174250 funded by the University of Salerno. AEP and JLC thank the Spanish Ministry of Economy and Competitiveness through RTI2018-101784-B-I00 and SEV-2016-0683 for the financial support. J.L. Cerrillo wishes to thank the Spanish Ministry of Economy and Competitiveness for the Severo Ochoa PhD fellowship (SVP-2014-068600). es_ES
dc.language Inglés es_ES
dc.publisher MDPI AG es_ES
dc.relation.ispartof Catalysts es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject Trichloroethylene es_ES
dc.subject Mayenite es_ES
dc.subject Catalytic oxidation es_ES
dc.subject Iron es_ES
dc.subject Chlorine poisoning es_ES
dc.subject.classification INGENIERIA QUIMICA es_ES
dc.title Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.3390/catal9090747 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068600/ES/SVP-2014-068600/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101784-B-I00/ES/NUEVOS MATERIALES ZEOLITICOS PARA PROCESOS DE SEPARACION SELECTIVA DE GASES, APLICACIONES MEDIOAMBIENTALES Y CONSERVACION DE ALIMENTOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNISA//ORSA167988/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/UNISA//ORSA174250/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Química y Nuclear - Departament d'Enginyeria Química i Nuclear es_ES
dc.description.bibliographicCitation Cucciniello, R.; Intiso, A.; Siciliano, T.; Palomares Gimeno, AE.; Martínez-Triguero, J.; Cerrillo, JL.; Proto, A.... (2019). Oxidative Degradation of Trichloroethylene over Fe2O3-doped Mayenite: Chlorine Poisoning Mitigation and Improved Catalytic Performance. Catalysts. 9(9):1-13. https://doi.org/10.3390/catal9090747 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.3390/catal9090747 es_ES
dc.description.upvformatpinicio 1 es_ES
dc.description.upvformatpfin 13 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 9 es_ES
dc.description.issue 9 es_ES
dc.identifier.eissn 2073-4344 es_ES
dc.relation.pasarela S\411689 es_ES
dc.contributor.funder Università degli Studi di Salerno es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
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