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Co and La supported on Zn-Hydrotalcite-derived material as efficient catalyst for ethanol steam reforming

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Co and La supported on Zn-Hydrotalcite-derived material as efficient catalyst for ethanol steam reforming

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Nombre: Cerdá-Moreno;Da;Chica ...
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dc.contributor.author Cerdá-Moreno, Cristina es_ES
dc.contributor.author Da Costa Serra, Javier Francisco es_ES
dc.contributor.author Chica, Antonio es_ES
dc.date.accessioned 2021-01-21T04:32:00Z
dc.date.available 2021-01-21T04:32:00Z
dc.date.issued 2019-05-17 es_ES
dc.identifier.issn 0360-3199 es_ES
dc.identifier.uri http://hdl.handle.net/10251/159607
dc.description.abstract [EN] Four samples of Zn-hydrotalcite containing different amounts of Co (5, 10, 20, and 30 wt%) have been synthesized and tested in the steam reforming of ethanol. The best results were obtained with the sample containing 20 wt% of Co (20CoHT), with a complete conversion of ethanol and yields to hydrogen close to the equilibrium (73 mol.%). The physicochemical characterization of the samples by DRX, BET area and TPR indicates that the excellent performance exhibited by the sample containing 20 wt% of Co is due to the higher percentage of reduced cobalt and lower crystallite size of metallic cobalt present in this sample (11 nm). Additional studies have been carried out to improve the stability of this catalytic material against deactivation by the incorporation of 1 wt% of La. Stability studies were carried out using an industrial alcoholic waste as feed. Deactivation after 24 h of reaction time was found lower for the catalyst containing La (20CoLaHT), confirming the positive effect of lanthanum on the catalytic stability. The results presented here show that it is possible to prepare a catalyst based on Co supported on Zn-hydrotalcite and promoted with La with improved ethanol conversion, high hydrogen selectivity, and high stability to produce hydrogen by the steam reforming of an industrial alcoholic waste without commercial value. es_ES
dc.description.sponsorship Cristina Cerda-Moreno acknowledges the financial support from the Spanish Government through predoctoral training fellowships for "Centros de Excelencia Severo Ochoa" (SEV-2016-0683). The doctor Javier Francisco Da Costa Serra wants to have some words of thanks toward CSIC for granted the scholarship predoctoral-JAE-CSIC. We also thanks to Destilerias San Valero for supplying us the samples of the alcoholic wastes used in this work. es_ES
dc.language Inglés es_ES
dc.publisher Elsevier es_ES
dc.relation.ispartof International Journal of Hydrogen Energy es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Ethanol steam reforming es_ES
dc.subject Hydrogen production es_ES
dc.subject Hydrotalcite es_ES
dc.subject LDHs es_ES
dc.subject Cobalt catalyst es_ES
dc.subject Alcoholic waste es_ES
dc.title Co and La supported on Zn-Hydrotalcite-derived material as efficient catalyst for ethanol steam reforming es_ES
dc.type Artículo es_ES
dc.type Comunicación en congreso es_ES
dc.identifier.doi 10.1016/j.ijhydene.2019.01.156 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SEV-2016-0683/ es_ES
dc.rights.accessRights Cerrado es_ES
dc.description.bibliographicCitation Cerdá-Moreno, C.; Da Costa Serra, JF.; Chica, A. (2019). Co and La supported on Zn-Hydrotalcite-derived material as efficient catalyst for ethanol steam reforming. International Journal of Hydrogen Energy. 44(25):12685-12692. https://doi.org/10.1016/j.ijhydene.2019.01.156 es_ES
dc.description.accrualMethod S es_ES
dc.relation.conferencename European Hydrogen Energy Conference (EHEC 2018) es_ES
dc.relation.conferencedate Marzo 14-16,2018 es_ES
dc.relation.conferenceplace Málaga, Spain es_ES
dc.relation.publisherversion https://doi.org/10.1016/j.ijhydene.2019.01.156 es_ES
dc.description.upvformatpinicio 12685 es_ES
dc.description.upvformatpfin 12692 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 44 es_ES
dc.description.issue 25 es_ES
dc.relation.pasarela S\377704 es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Consejo Superior de Investigaciones Científicas es_ES
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dc.subject.ods 07.- Asegurar el acceso a energías asequibles, fiables, sostenibles y modernas para todos es_ES


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