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Influence of the Nature of the Promoter in NiO Catalysts on the Selectivity to Olefin During the Oxidative Dehydrogenation of Propane and Ethane

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Influence of the Nature of the Promoter in NiO Catalysts on the Selectivity to Olefin During the Oxidative Dehydrogenation of Propane and Ethane

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dc.contributor.author Delgado Muñoz, Daniel es_ES
dc.contributor.author Sanchis, Rut es_ES
dc.contributor.author Solsona Espriu, Benjamin Eduardo es_ES
dc.contributor.author Concepción Heydorn, Patricia es_ES
dc.contributor.author López Nieto, José Manuel es_ES
dc.date.accessioned 2022-06-01T18:07:18Z
dc.date.available 2022-06-01T18:07:18Z
dc.date.issued 2020-12 es_ES
dc.identifier.issn 1022-5528 es_ES
dc.identifier.uri http://hdl.handle.net/10251/183042
dc.description.abstract [EN] A comparative study of the catalytic properties for the oxidation of C2-C3 alkanes and olefins has been carried out over unpromoted and M-promoted NiO catalysts (Me¿=¿K, La, Ce, al, Zr, Sn, Nb). The catalysts have been characterized by several physico-chemical techniques (UV Raman, Visible Raman, FTIR of adsorbed CO and XPS). The characteristics of promoter elements are of paramount importance, since they are able to modify both the nature of the active nickel and the concentration of electrophilic O2¿/O¿ oxygen species. Thus, a relatively high acidity and valence of the promoter oxide (with oxidation state higher than¿+¿3) are necessary to achieve high selectivity to olefins during the oxidative dehydrogenation (ODH) of C2¿C3 alkanes. In addition, an inverse correlation between the selectivity to the corresponding olefin and the concentration of electrophilic oxygen species has been observed, although the selectivity to propene during propane ODH is lower than the selectivity to ethylene achieved during ethane ODH. On the other hand, a very low influence of alkane conversion on the selectivity to the corresponding olefins is observed. This behaviour can be explained by considering that the reaction rate for olefin combustion is lower than the reaction rate for alkane oxidation. However, the comparative study of the oxidation of alkanes and olefins suggest that the differences observed between the ODH of propane and ethane are not related to the reactivity of olefins, but to the different number and reactivity of C¿H bonds in both alkanes. A discussion on the importance of the concentration of active sites and the characteristics of the alkanes fed on the selectivity to olefin during the alkane ODH is also presented. es_ES
dc.description.sponsorship The authors would like to acknowledge the Ministerio de Ciencia, Innovacion y Universidades of Spain (RTl2018-099668-B-C21 and MAT2017-84118-C2-1-R projects) and FEDER. Authors from ITQ also thank Project SEV-2016-0683 for supporting this research. D.D. thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). es_ES
dc.language Inglés es_ES
dc.publisher Springer-Verlag es_ES
dc.relation.ispartof Topics in Catalysis es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Propane es_ES
dc.subject Ethane es_ES
dc.subject Oxidative dehydrogenation es_ES
dc.subject Olefins es_ES
dc.subject Promoters es_ES
dc.subject Nickel oxide es_ES
dc.title Influence of the Nature of the Promoter in NiO Catalysts on the Selectivity to Olefin During the Oxidative Dehydrogenation of Propane and Ethane es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s11244-020-01329-5 es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-84118-C2-1-R/ES/VALORIZACION DE RECURSOS NATURALES COMO NUEVOS MATERIALES AVANZADOS :APLICACIONES CATALITICAS Y ELECTROQUIMICAS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//SVP-2014-068669//SVP-2014-068669/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-099668-B-C21/ES/VALORIZACION DE CO2: CAPTURA, Y TRANSFORMACION CATALITICA PARA ALMACENAMIENTO DE ENERGIA, COMBUSTIBLES Y PRODUCTOS QUIMICOS/ es_ES
dc.relation.projectID info:eu-repo/grantAgreement/MCIU//SEV-2016-0683/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.description.bibliographicCitation Delgado Muñoz, D.; Sanchis, R.; Solsona Espriu, BE.; Concepción Heydorn, P.; López Nieto, JM. (2020). Influence of the Nature of the Promoter in NiO Catalysts on the Selectivity to Olefin During the Oxidative Dehydrogenation of Propane and Ethane. Topics in Catalysis. 63(19-20):1731-1742. https://doi.org/10.1007/s11244-020-01329-5 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion https://doi.org/10.1007/s11244-020-01329-5 es_ES
dc.description.upvformatpinicio 1731 es_ES
dc.description.upvformatpfin 1742 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 63 es_ES
dc.description.issue 19-20 es_ES
dc.relation.pasarela S\431392 es_ES
dc.contributor.funder Agencia Estatal de Investigación es_ES
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades es_ES
dc.contributor.funder Comisión Interministerial de Ciencia y Tecnología es_ES
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