- -

Regioselective Hydration of Alkynes by Iron(III) Lewis/Brønsted Catalysis

RiuNet: Institutional repository of the Polithecnic University of Valencia

Share/Send to

Cited by

Statistics

Regioselective Hydration of Alkynes by Iron(III) Lewis/Brønsted Catalysis

Show full item record

Cabrero Antonino, JR.; Leyva Perez, A.; Corma Canós, A. (2012). Regioselective Hydration of Alkynes by Iron(III) Lewis/Brønsted Catalysis. Chemistry - A European Journal. 18(35):11107-11114. doi:10.1002/chem.201200580

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10251/33630

Files in this item

Item Metadata

Title: Regioselective Hydration of Alkynes by Iron(III) Lewis/Brønsted Catalysis
Author:
UPV Unit: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Issued date:
Abstract:
The triflimide iron(III) salt [Fe(NTf2)3] promotes the direct hydration of terminal and internal alkynes with very good Markovnikov regioselectivities and high yields. The enhanced carbophilic Lewis acidity of the FeIII ...[+]
Subjects: Alkynes , Anions , Ketones , Regioselectivity , Iron , Hydration
Copyrigths: Cerrado
Source:
Chemistry - A European Journal. (issn: 0947-6539 )
DOI: 10.1002/chem.201200580
Publisher:
Wiley-VCH Verlag
Publisher version: http://dx.doi.org/10.1002/chem.201200580
Thanks:
The work has been supported by Consolider-Ingenio 2010 (proyecto MULTICAT), and PROMETEO from Generalitat Valenciana. J.R.C.A. thanks MCIINN for a pre-doctoral FPU fellowship. A. L. P. thanks ITQ for financial support. We ...[+]
Type: Artículo

This item appears in the following Collection(s)

Show full item record