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Enantioselective Synthesis of 4-Substituted Dihydrocoumarins through a Zinc Bis(hydroxyamide)-Catalyzed Conjugate Addition of Terminal Alkynes

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Enantioselective Synthesis of 4-Substituted Dihydrocoumarins through a Zinc Bis(hydroxyamide)-Catalyzed Conjugate Addition of Terminal Alkynes

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Blay, G.; Muñoz Roca, MDC.; Pedro, JR.; Sanz-Marco, A. (2013). Enantioselective Synthesis of 4-Substituted Dihydrocoumarins through a Zinc Bis(hydroxyamide)-Catalyzed Conjugate Addition of Terminal Alkynes. Advanced Synthesis and Catalysis. 355:1071-1076. https://doi.org/10.1002/adsc.201201120

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Metadatos del ítem

Título: Enantioselective Synthesis of 4-Substituted Dihydrocoumarins through a Zinc Bis(hydroxyamide)-Catalyzed Conjugate Addition of Terminal Alkynes
Autor: Blay, Gonzalo Muñoz Roca, María del Carmen Pedro, Jose R Sanz-Marco, Amparo
Entidad UPV: Universitat Politècnica de València. Departamento de Física Aplicada - Departament de Física Aplicada
Fecha difusión:
Resumen:
A new enantioselective catalyst for the conjugate addition of terminal alkynes has been developed. Terminal alkynes react with 3-alkoxycarbonylcoumarins in the presence of diethylzinc and bis(hydroxyamide) ligands to ...[+]
Palabras clave: Alkynylation , Asymmetric catalysis , Nucleophilic addition , Oxygen heterocycles , N, O ligands
Derechos de uso: Cerrado
Fuente:
Advanced Synthesis and Catalysis. (issn: 1615-4150 )
DOI: 10.1002/adsc.201201120
Editorial:
Wiley-VCH Verlag
Versión del editor: http://dx.doi.org/10.1002/adsc.201201120
Código del Proyecto:
info:eu-repo/grantAgreement/MICINN//CTQ2009-13083/ES/Desarrollo de nuevos procesos enantioselectivos de formación de enlaces C-C mediante catálisis asimétrica/
info:eu-repo/grantAgreement/GVA//ISIC2012%2F001/
info:eu-repo/grantAgreement/GVA//ACOMP%2F2012%2F212/
Agradecimientos:
Financial support from the Ministerio de Economia y Competitividad (Gobierno de Espana) and FEDER (European Union) (CTQ2009-13083) and from Generalitat Valenciana (ACOMP2012-212 and ISIC2012/001) is gratefully acknowledged. ...[+]
Tipo: Artículo

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