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A bifunctional palladium-acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

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A bifunctional palladium-acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

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Rubio Marqués, P.; Leyva Perez, A.; Corma Canós, A. (2013). A bifunctional palladium-acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes. Chemical Communications. 49(74):8160-8162. https://doi.org/10.1039/c3cc44064h

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Título: A bifunctional palladium-acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes
Autor: Rubio Marqués, Paula Leyva Perez, Antonio Corma Canós, Avelino
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
[EN] Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Bronsted acid.[+]
Palabras clave: Nitro-compounds , Gold catalysts , Amines , Alcohols , Hydrogenation , Nitroarenes , Amination
Derechos de uso: Reserva de todos los derechos
Fuente:
Chemical Communications. (issn: 1359-7345 )
DOI: 10.1039/c3cc44064h
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/C3CC44064H
Código del Proyecto:
info:eu-repo/grantAgreement/MINECO//SEV-2012-0267/
info:eu-repo/grantAgreement/MICINN//MAT2009-00889/
Agradecimientos:
Financial support by Consolider-Ingenio MULTICAT 2010, subprograma de Apoyo a Centros y Universidades de Excelencia Severo Ochoa (SEV 2012 0267), and MAT2009-00889 projects from MICINN is acknowledged. P. R.-M. thanks the ...[+]
Tipo: Artículo

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