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Surface modification of polypropylene substrates by UV photografting of methyl methacrylate (MMA) for improved surface wettability

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Surface modification of polypropylene substrates by UV photografting of methyl methacrylate (MMA) for improved surface wettability

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dc.contributor.author Balart Gimeno, Javier Francisco es_ES
dc.contributor.author Fombuena Borrás, Vicent es_ES
dc.contributor.author Boronat Vitoria, Teodomiro es_ES
dc.contributor.author Reig Pérez, Miguel Jorge es_ES
dc.contributor.author Balart Gimeno, Rafael Antonio es_ES
dc.date.accessioned 2015-03-27T16:52:38Z
dc.date.available 2015-03-27T16:52:38Z
dc.date.issued 2012-03
dc.identifier.issn 0022-2461
dc.identifier.uri http://hdl.handle.net/10251/48418
dc.description The final publication is available at Springer via http://dx.doi.org/10.1007/s10853-011-6056-9 es_ES
dc.description.abstract Despite polypropylene is one of the most used commodity plastics, its adhesion properties are remarkably restricted by its non-polar nature which leads to low wetting properties and, consequently, poor adhesion behavior. We report the use of ultraviolet photografting process of methyl methacrylate (MMA) monomer as an efficient chemical treatment for surface activation of polypropylene. Contact angle measurements are used for evaluating changes in polypropylene wetting properties together with surface free energy calculations. Chemical changes are showed in terms of the exposure time to UV radiation. Scanning electron microscopy has been used to evaluate topography changes in a qualitative way; atomic force microscopy has been used for a quantitative evaluation of surface changes in terms of roughness. The use of Fourier transformed infrared spectroscopy has revealed the nature of the chemical changes induced by the photografting process of MMA. © 2011 Springer Science+Business Media, LLC. es_ES
dc.description.sponsorship This study is a part of the project IPT-310000-2010-037, "ECOTEXCOMP: Research and development of textile structures useful as reinforcement of composite materials with marked ecological character" funded by the "Ministerio de Ciencia e Innovacion," with an aid of 189540.20 euros, within the "Plan Nacional de Investigacion Cientifica, Desarrollo e Innovacion Tecnologica 2008-2011" and funded by the European Union through FEDER funds, Technology Fund 2007-2013, Operational Programme on R + D + i for and on behalf of the companies." Also, microscopy services at UPV are acknowledged for SEM and AFM support. en_EN
dc.language Inglés es_ES
dc.publisher Springer Verlag (Germany) es_ES
dc.relation.ispartof Journal of Materials Science es_ES
dc.rights Reserva de todos los derechos es_ES
dc.subject Adhesion properties es_ES
dc.subject Chemical change es_ES
dc.subject Chemical treatments es_ES
dc.subject Commodity plastics es_ES
dc.subject Exposure-time es_ES
dc.subject Fourier transformed infrared spectroscopy es_ES
dc.subject Methyl methacrylates es_ES
dc.subject Non-polar es_ES
dc.subject Photo-grafting es_ES
dc.subject Poor adhesion es_ES
dc.subject Quantitative evaluation es_ES
dc.subject Surface activation es_ES
dc.subject Surface changes es_ES
dc.subject Surface free energy es_ES
dc.subject Surface wettability es_ES
dc.subject UV-photografting es_ES
dc.subject Wetting property es_ES
dc.subject Adhesion es_ES
dc.subject Atomic force microscopy es_ES
dc.subject Contact angle es_ES
dc.subject Esters es_ES
dc.subject Grafting (chemical) es_ES
dc.subject Infrared spectroscopy es_ES
dc.subject Plastic products es_ES
dc.subject Quality control es_ES
dc.subject Scanning electron microscopy es_ES
dc.subject Thermoplastics es_ES
dc.subject Ultraviolet radiation es_ES
dc.subject Wetting es_ES
dc.subject Polypropylenes es_ES
dc.subject.classification CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA es_ES
dc.subject.classification INGENIERIA DE LOS PROCESOS DE FABRICACION es_ES
dc.title Surface modification of polypropylene substrates by UV photografting of methyl methacrylate (MMA) for improved surface wettability es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1007/s10853-011-6056-9
dc.relation.projectID info:eu-repo/grantAgreement/MICINN//IPT-310000-2010-037/ES/ECOTEXCOMP: Investigación y desarrollo de estructuras textiles aplicables como refuerzo de materiales compuestos de marcado carácter ecológico/
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Ingeniería Mecánica y de Materiales - Departament d'Enginyeria Mecànica i de Materials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto de Tecnología de Materiales - Institut de Tecnologia de Materials es_ES
dc.description.bibliographicCitation Balart Gimeno, JF.; Fombuena Borrás, V.; Boronat Vitoria, T.; Reig Pérez, MJ.; Balart Gimeno, RA. (2012). Surface modification of polypropylene substrates by UV photografting of methyl methacrylate (MMA) for improved surface wettability. Journal of Materials Science. 47(5):2375-2383. doi:10.1007/s10853-011-6056-9 es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://dx.doi.org/10.1007/s10853-011-6056-9 es_ES
dc.description.upvformatpinicio 2375 es_ES
dc.description.upvformatpfin 2383 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 47 es_ES
dc.description.issue 5 es_ES
dc.relation.senia 207412
dc.identifier.eissn 1573-4803
dc.contributor.funder Ministerio de Ciencia e Innovación es_ES
dc.contributor.funder European Commission
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