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Translocation versus cyclisation in radicals derived from N-3-alkenyl trichloroacetamides

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Translocation versus cyclisation in radicals derived from N-3-alkenyl trichloroacetamides

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Marín García, ML.; Zaragoza, RJ.; Miranda Alonso, MÁ.; Diaba, F.; Bonjoch, J. (2011). Translocation versus cyclisation in radicals derived from N-3-alkenyl trichloroacetamides. Organic and Biomolecular Chemistry. 9(9):3180-3187. https://doi.org/10.1039/c0ob01228a

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Título: Translocation versus cyclisation in radicals derived from N-3-alkenyl trichloroacetamides
Autor: Marín García, Mª Luisa Zaragoza, Ramon J. Miranda Alonso, Miguel Ángel Diaba, Faiza Bonjoch, Josep
Entidad UPV: Universitat Politècnica de València. Departamento de Química - Departament de Química
Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química
Fecha difusión:
Resumen:
Under radical reaction conditions, two different and competitive reaction pathways were observed for N-(alpha-methylbenzyl)trichloroacetamides with a N-3-cyclohexenyl substituent: 1,4-hydrogen translocation and radical ...[+]
Palabras clave: POLARIZABLE CONTINUUM MODEL , COPPER-COMPLEXES , AMIDES , TOOL
Derechos de uso: Reserva de todos los derechos
Fuente:
Organic and Biomolecular Chemistry. (issn: 1477-0520 )
DOI: 10.1039/c0ob01228a
Editorial:
Royal Society of Chemistry
Versión del editor: http://dx.doi.org/10.1039/c0ob01228a
Código del Proyecto:
info:eu-repo/grantAgreement/MEC//CTQ2007-61338/ES/CARBO- Y AZABICICLOS ENANTIOPUROS MEDIANTE ORGANOCATALISIS Y PROCESOS CATALIZADOS POR CU(I). SINTESIS TOTAL DE ALCALOIDES Y TERPENOIDES DE ELEVADA COMPLEJIDAD ESTRUCTURAL/
info:eu-repo/grantAgreement/UPV//2005-PPI-06-05/
info:eu-repo/grantAgreement/MICINN//CTQ2009-11027/ES/Estudios de reactividad en química orgánica/
info:eu-repo/grantAgreement/MICINN//CTQ2009-13699/ES/CTQ2009-13699/
Agradecimientos:
This research was supported by the Ministry of Education and Science (Spain)-FEDER through projects CTQ2007-61338/BQU, CTQ2009-11027/BQU and CTQ2009-13699 and Universidad Politecnica de Valencia (2005-PPI-06-05).
Tipo: Artículo

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