- -

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

RiuNet: Repositorio Institucional de la Universidad Politécnica de Valencia

Compartir/Enviar a

Citas

Estadísticas

  • Estadisticas de Uso

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

Mostrar el registro sencillo del ítem

Ficheros en el ítem

Thumbnail
Nombre: Cabrero;Tejeda-Se ...
Tamaño: 1.911Mb
Formato: PDF
Descripción: Versión editorial
Abrir
dc.contributor.author Cabrero Antonino, Jose Ramón es_ES
dc.contributor.author Tejeda-Serrano, Maria es_ES
dc.contributor.author Quesada Vilar, Manuel es_ES
dc.contributor.author Vidal Moya, José Alejandro es_ES
dc.contributor.author Leyva Perez, Antonio es_ES
dc.contributor.author Corma Canós, Avelino es_ES
dc.date.accessioned 2017-05-19T11:50:37Z
dc.date.available 2017-05-19T11:50:37Z
dc.date.issued 2017
dc.identifier.issn 2041-6520
dc.identifier.uri http://hdl.handle.net/10251/81494
dc.description.abstract A new approach is presented to form self-supported bimetallic nanosized solids with acid and redox catalytic properties. They are water-, air- and H-2-stable, and are able to activate demanding C-C and C-H reactions. A detailed mechanistic study on the formation of the Ag-Fe bimetallic system shows that a rapid redox-coupled sequence between Ag+, O-2 (air) and Fe2+ occurs, giving monodisperse Ag nanoparticles supported by O-bridged diatomic Fe3+ triflimides. The system can be expanded to Ag nanoparticles embedded within a matrix of Cu2+, Bi3+ and Yb3+ triflimide. es_ES
dc.description.sponsorship Financial support by the "Severo Ochoa" program, RETOS program (CTQ2014-55178 R) and Ramon y Cajal Program (A.L.-P.) by MINECO (Spain), and also by "Convocatoria 2014 de Ayudas Fundacion BBVA a Investigadores y Creadores Culturales" are acknowledged. The Electron Microscopy Service of the UPV is also acknowledged. en_EN
dc.language Inglés es_ES
dc.publisher Royal Society of Chemistry es_ES
dc.relation "Severo Ochoa" program by MINECO (Spain) es_ES
dc.relation.ispartof Chemical Science es_ES
dc.rights Reconocimiento (by) es_ES
dc.subject 1,3-DICARBONYL COMPOUNDS es_ES
dc.subject ORGANIC-SYNTHESIS es_ES
dc.subject SILVER NANOPARTICLES es_ES
dc.subject ROOM-TEMPERATURE es_ES
dc.subject ALKYNES es_ES
dc.subject DIMERIZATION es_ES
dc.subject HYDRATION es_ES
dc.subject STYRENES es_ES
dc.subject OXIDATIONS es_ES
dc.subject COMPLEXES es_ES
dc.subject Electron Microscopy Service of the UPV
dc.subject.classification QUIMICA ORGANICA es_ES
dc.subject.classification QUIMICA ANALITICA es_ES
dc.title Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds es_ES
dc.type Artículo es_ES
dc.identifier.doi 10.1039/c6sc03335k
dc.relation.projectID info:eu-repo/grantAgreement/MINECO//CTQ2014-55178-R/ES/HIERRO Y BISMUTO SUB-NANOMETRICO Y CATALITICO/ es_ES
dc.rights.accessRights Abierto es_ES
dc.contributor.affiliation Universitat Politècnica de València. Escuela Técnica Superior de Ingenieros Industriales - Escola Tècnica Superior d'Enginyers Industrials es_ES
dc.contributor.affiliation Universitat Politècnica de València. Instituto Universitario Mixto de Tecnología Química - Institut Universitari Mixt de Tecnologia Química es_ES
dc.contributor.affiliation Universitat Politècnica de València. Departamento de Química - Departament de Química es_ES
dc.description.bibliographicCitation Cabrero Antonino, JR.; Tejeda-Serrano, M.; Quesada Vilar, M.; Vidal Moya, JA.; Leyva Perez, A.; Corma Canós, A. (2017). Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds. Chemical Science. 8(1):689-696. https://doi.org/10.1039/c6sc03335k es_ES
dc.description.accrualMethod S es_ES
dc.relation.publisherversion http://doi.org/10.1039/c6sc03335k es_ES
dc.description.upvformatpinicio 689 es_ES
dc.description.upvformatpfin 696 es_ES
dc.type.version info:eu-repo/semantics/publishedVersion es_ES
dc.description.volume 8 es_ES
dc.description.issue 1 es_ES
dc.relation.senia 328383 es_ES
dc.identifier.eissn 2041-6539
dc.identifier.pmcid PMC5297923
dc.contributor.funder Ministerio de Economía y Competitividad es_ES
dc.contributor.funder Fundación BBVA es_ES
dc.description.references Antoniotti, S., Dalla, V., & Duñach, E. (2010). Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis-The Effect of a Highly Delocalized Counteranion. Angewandte Chemie International Edition, 49(43), 7860-7888. doi:10.1002/anie.200906407 es_ES
dc.description.references White, M. C. (2012). Adding Aliphatic C-H Bond Oxidations to Synthesis. Science, 335(6070), 807-809. doi:10.1126/science.1207661 es_ES
dc.description.references Felpin, F.-X., & Fouquet, E. (2008). Heterogeneous Multifunctional Catalysts for Tandem Processes: An Approach toward Sustainability. ChemSusChem, 1(8-9), 718-724. doi:10.1002/cssc.200800110 es_ES
dc.description.references Díaz, U., Brunel, D., & Corma, A. (2013). Catalysis using multifunctional organosiliceous hybrid materials. Chemical Society Reviews, 42(9), 4083. doi:10.1039/c2cs35385g es_ES
dc.description.references Rey, I., Johansson, P., Lindgren, J., Lassègues, J. C., Grondin, J., & Servant, L. (1998). Spectroscopic and Theoretical Study of (CF3SO2)2N-(TFSI-) and (CF3SO2)2NH (HTFSI). The Journal of Physical Chemistry A, 102(19), 3249-3258. doi:10.1021/jp980375v es_ES
dc.description.references Kurtz, D. M. (1990). Oxo- and hydroxo-bridged diiron complexes: a chemical perspective on a biological unit. Chemical Reviews, 90(4), 585-606. doi:10.1021/cr00102a002 es_ES
dc.description.references Cabrero-Antonino, J. R., Leyva-Pérez, A., & Corma, A. (2012). Regioselective Hydration of Alkynes by Iron(III) Lewis/Brønsted Catalysis. Chemistry - A European Journal, 18(35), 11107-11114. doi:10.1002/chem.201200580 es_ES
dc.description.references Desireddy, A., Conn, B. E., Guo, J., Yoon, B., Barnett, R. N., Monahan, B. M., … Bigioni, T. P. (2013). Ultrastable silver nanoparticles. Nature, 501(7467), 399-402. doi:10.1038/nature12523 es_ES
dc.description.references Skupinska, J. (1991). Oligomerization of .alpha.-olefins to higher oligomers. Chemical Reviews, 91(4), 613-648. doi:10.1021/cr00004a007 es_ES
dc.description.references Choi, J. H., Kwon, J. K., RajanBabu, T. V., & Lim, H. J. (2013). Highly Efficient Catalytic Dimerization of StyrenesviaCationic Palladium(II) Complexes. Advanced Synthesis & Catalysis, 355(18), 3633-3638. doi:10.1002/adsc.201300864 es_ES
dc.description.references Bedford, R. B., Betham, M., Blake, M. E., Garcés, A., Millar, S. L., & Prashar, S. (2005). Asymmetric styrene dimerisation using mixed palladium–indium catalysts. Tetrahedron, 61(41), 9799-9807. doi:10.1016/j.tet.2005.06.083 es_ES
dc.description.references Wang, C.-C., Lin, P.-S., & Cheng, C.-H. (2004). Cobalt-catalyzed dimerization of alkenes. Tetrahedron Letters, 45(32), 6203-6206. doi:10.1016/j.tetlet.2004.04.085 es_ES
dc.description.references Cabrero-Antonino, J. R., Leyva-Pérez, A., & Corma, A. (2010). Iron-Catalysed Regio- and Stereoselective Head-to-Tail Dimerisation of Styrenes. Advanced Synthesis & Catalysis, 352(10), 1571-1576. doi:10.1002/adsc.201000096 es_ES
dc.description.references Shimura, S., Miura, H., Tsukada, S., Wada, K., Hosokawa, S., & Inoue, M. (2012). Highly Selective Linear Dimerization of Styrenes by Ceria-Supported Ruthenium Catalysts. ChemCatChem, 4(12), 2062-2067. doi:10.1002/cctc.201200342 es_ES
dc.description.references Hintermann, L., & Labonne, A. (2007). Catalytic Hydration of Alkynes and Its Application in Synthesis. Synthesis, 2007(8), 1121-1150. doi:10.1055/s-2007-966002 es_ES
dc.description.references Ebule, R. E., Malhotra, D., Hammond, G. B., & Xu, B. (2016). Ligand Effects in the Gold Catalyzed Hydration of Alkynes. Advanced Synthesis & Catalysis, 358(9), 1478-1481. doi:10.1002/adsc.201501079 es_ES
dc.description.references Liang, S., Jasinski, J., Hammond, G. B., & Xu, B. (2014). Supported Gold Nanoparticle-Catalyzed Hydration of Alkynes under Basic Conditions. Organic Letters, 17(1), 162-165. doi:10.1021/ol5033859 es_ES
dc.description.references Leyva, A., & Corma, A. (2009). Isolable Gold(I) Complexes Having One Low-Coordinating Ligand as Catalysts for the Selective Hydration of Substituted Alkynes at Room Temperature without Acidic Promoters. The Journal of Organic Chemistry, 74(5), 2067-2074. doi:10.1021/jo802558e es_ES
dc.description.references Nairoukh, Z., Avnir, D., & Blum, J. (2013). Acid-Catalyzed Hydration of Alkynes in Aqueous Microemulsions. ChemSusChem, 6(3), 430-432. doi:10.1002/cssc.201200838 es_ES
dc.description.references Mameda, N., Peraka, S., Marri, M. R., Kodumuri, S., Chevella, D., Gutta, N., & Nama, N. (2015). Solvent-free hydration of alkynes over Hβ zeolite. Applied Catalysis A: General, 505, 213-216. doi:10.1016/j.apcata.2015.07.038 es_ES
dc.description.references Alonso, F., Beletskaya, I. P., & Yus, M. (2004). Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes. Chemical Reviews, 104(6), 3079-3160. doi:10.1021/cr0201068 es_ES
dc.description.references Lennon, P., Rosan, A. M., & Rosenblum, M. (1977). Metal assisted carbon-carbon bond formation. Addition of carbon nucleophiles to dicarbonyl .eta.5-cyclopentadienyl(olefin)iron cations. Journal of the American Chemical Society, 99(26), 8426-8439. doi:10.1021/ja00468a009 es_ES
dc.description.references Qian, H., & Widenhoefer, R. A. (2003). Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 7-Octene-2,4-dione. Journal of the American Chemical Society, 125(8), 2056-2057. doi:10.1021/ja0293002 es_ES
dc.description.references Kischel, J., Michalik, D., Zapf, A., & Beller, M. (2007). FeCl3-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Aromatic Olefins. Chemistry – An Asian Journal, 2(7), 909-914. doi:10.1002/asia.200700055 es_ES
dc.description.references Huber, G. W., Iborra, S., & Corma, A. (2006). Synthesis of Transportation Fuels from Biomass:  Chemistry, Catalysts, and Engineering. Chemical Reviews, 106(9), 4044-4098. doi:10.1021/cr068360d es_ES
dc.description.references Li, Z., Assary, R. S., Atesin, A. C., Curtiss, L. A., & Marks, T. J. (2013). Rapid Ether and Alcohol C–O Bond Hydrogenolysis Catalyzed by Tandem High-Valent Metal Triflate + Supported Pd Catalysts. Journal of the American Chemical Society, 136(1), 104-107. doi:10.1021/ja411546r es_ES
dc.description.references Corma, A., de la Torre, O., Renz, M., & Villandier, N. (2011). Production of High-Quality Diesel from Biomass Waste Products. Angewandte Chemie International Edition, 50(10), 2375-2378. doi:10.1002/anie.201007508 es_ES
dc.description.references Gelbard, G. (2005). Organic Synthesis by Catalysis with Ion-Exchange Resins. Industrial & Engineering Chemistry Research, 44(23), 8468-8498. doi:10.1021/ie0580405 es_ES
dc.description.references Cabrero-Antonino, J. R., Leyva-Pérez, A., & Corma, A. (2015). Beyond Acid Strength in Zeolites: Soft Framework Counteranions for Stabilization of Carbocations on Zeolites and Its Implication in Organic Synthesis. Angewandte Chemie International Edition, 54(19), 5658-5661. doi:10.1002/anie.201500864 es_ES
dc.description.references Arata, K. (2009). Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds. Green Chemistry, 11(11), 1719. doi:10.1039/b822795k es_ES
dc.description.references Tinberg, C. E., & Lippard, S. J. (2011). Dioxygen Activation in Soluble Methane Monooxygenase. Accounts of Chemical Research, 44(4), 280-288. doi:10.1021/ar1001473 es_ES
dc.description.references Leising, R. A., Kim, J., Perez, M. A., & Que, L. (1993). Alkane functionalization at (.mu.-oxo)diiron(III) centers. Journal of the American Chemical Society, 115(21), 9524-9530. doi:10.1021/ja00074a017 es_ES
dc.description.references Raffard-Pons Y Moll, N., Banse, F., Miki, K., Nierlich, M., & Girerd, J.-J. (2002). Hydroxylation of Hexane Using Dioxygen and Trimethylhydroquinone: Biomimetic Catalysis by an Unsymmetrical Diiron-μ-Oxo Complex. European Journal of Inorganic Chemistry, 2002(8), 1941-1944. doi:10.1002/1099-0682(200208)2002:8<1941::aid-ejic1941>3.0.co;2-b es_ES
dc.description.references Chen, M. S., & White, M. C. (2010). Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation. Science, 327(5965), 566-571. doi:10.1126/science.1183602 es_ES
dc.description.references Gormisky, P. E., & White, M. C. (2013). Catalyst-Controlled Aliphatic C–H Oxidations with a Predictive Model for Site-Selectivity. Journal of the American Chemical Society, 135(38), 14052-14055. doi:10.1021/ja407388y es_ES
dc.description.references Corma, A., Nemeth, L. T., Renz, M., & Valencia, S. (2001). Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations. Nature, 412(6845), 423-425. doi:10.1038/35086546 es_ES
dc.description.references Cabrero-Antonino, J. R., Leyva-Pérez, A., & Corma, A. (2012). Iron-Catalysed Markovnikov Hydrothiolation of Styrenes. Advanced Synthesis & Catalysis, 354(4), 678-687. doi:10.1002/adsc.201100731 es_ES
dc.description.references Castarlenas, R., Di Giuseppe, A., Pérez-Torrente, J. J., & Oro, L. A. (2012). The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook. Angewandte Chemie International Edition, 52(1), 211-222. doi:10.1002/anie.201205468 es_ES
dc.description.references Baciocchi, E., Lanzalunga, O., Lapi, A., & Manduchi, L. (1998). Kinetic Deuterium Isotope Effect Profiles and Substituent Effects in the Oxidative N-Demethylation ofN,N-Dimethylanilines Catalyzed by Tetrakis(pentafluorophenyl)porphyrin Iron(III) Chloride. Journal of the American Chemical Society, 120(23), 5783-5787. doi:10.1021/ja980187i es_ES
dc.description.references Zhang, J., Wang, Y., Luo, N., Chen, Z., Wu, K., & Yin, G. (2015). Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases. Dalton Transactions, 44(21), 9847-9859. doi:10.1039/c5dt00804b es_ES
dc.description.references Leyva-Pérez, A., García-García, P., & Corma, A. (2014). Multisite Organic-Inorganic Hybrid Catalysts for the Direct Sustainable Synthesis of GABAergic Drugs. Angewandte Chemie International Edition, 53(33), 8687-8690. doi:10.1002/anie.201403049 es_ES
dc.description.references Xu, R., Wang, D., Zhang, J., & Li, Y. (2006). Shape-Dependent Catalytic Activity of Silver Nanoparticles for the Oxidation of Styrene. Chemistry – An Asian Journal, 1(6), 888-893. doi:10.1002/asia.200600260 es_ES
dc.description.references Mitsudome, T., Mikami, Y., Funai, H., Mizugaki, T., Jitsukawa, K., & Kaneda, K. (2008). Oxidant-Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite-Supported Silver Nanoparticle Catalyst. Angewandte Chemie International Edition, 47(1), 138-141. doi:10.1002/anie.200703161 es_ES
dc.description.references Cai, S., Rong, H., Yu, X., Liu, X., Wang, D., He, W., & Li, Y. (2013). Room Temperature Activation of Oxygen by Monodispersed Metal Nanoparticles: Oxidative Dehydrogenative Coupling of Anilines for Azobenzene Syntheses. ACS Catalysis, 3(4), 478-486. doi:10.1021/cs300707y es_ES
dc.description.references Qu, Z., Zhou, S., Wu, W., Li, C., & Bao, X. (2005). CO adsorption and correlation between CO surface coverage and activity/selectivity of preferential CO oxidation over supported Ag catalyst: an in situ FTIR study. Catalysis Letters, 101(1-2), 21-26. doi:10.1007/s10562-004-3742-0 es_ES
dc.description.references Huang, G.-B., Wang, X., Pan, Y.-M., Wang, H.-S., Yao, G.-Y., & Zhang, Y. (2013). Atom-Economical Chemoselective Synthesis of 1,4-Enynes from Terminal Alkenes and Propargylic Alcohols Catalyzed by Cu(OTf)2. The Journal of Organic Chemistry, 78(6), 2742-2745. doi:10.1021/jo3026803 es_ES
dc.description.references Kischel, J., Mertins, K., Michalik, D., Zapf, A., & Beller, M. (2007). A General and Efficient Iron-Catalyzed Benzylation of 1,3-Dicarbonyl Compounds. Advanced Synthesis & Catalysis, 349(6), 865-870. doi:10.1002/adsc.200600497 es_ES
dc.description.references Moriel, P., & García, A. B. (2014). Carbon-supported iron–ionic liquid: an efficient and recyclable catalyst for benzylation of 1,3-dicarbonyl compounds with alcohols. Green Chem., 16(9), 4306-4311. doi:10.1039/c4gc00755g es_ES
dc.description.references Wang, Z., Chen, G., & Ding, K. (2009). Self-Supported Catalysts. Chemical Reviews, 109(2), 322-359. doi:10.1021/cr800406u es_ES
dc.description.references Chen, H., Wang, D., Yu, Y., Newton, K. A., Muller, D. A., Abruña, H., & DiSalvo, F. J. (2012). A Surfactant-Free Strategy for Synthesizing and Processing Intermetallic Platinum-Based Nanoparticle Catalysts. Journal of the American Chemical Society, 134(44), 18453-18459. doi:10.1021/ja308674b es_ES


Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem