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Browsing by Author "Fischer, Roland A."

Now showing items 1-8 of 8

Au@MOF-5 and Au/MOx@MOF-5 (M = Zn, Ti; x = 1, 2): Preparation and Microstructural Characterisation

Müller, Maike; Stuart, Turner; Lebedev, Oleg, I.; Wang, Yuemin; Van Tendeloo, Gustaaf; Fischer, Roland A. (Wiley-VCH Verlag, 2011)

[EN] The Zn-carboxylate-based porous coordination polymer MOF-5 [Zn4O(bdc)(3)] and the metal oxide loaded materials ZnO@MOF-5 and TiO2@MOF-5 were loaded in a second step with the precursor [ClAuCO] to yield intermediate ...
Defect-Engineered Ruthenium MOFs as Versatile Heterogeneous Hydrogenation Catalysts

Epp, Konstantin; Luz, Ignacio; Heinz, Werner R.; Rapeyko, Anastasia; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A. (John Wiley & Sons, 2020-03-19)

[EN] Ruthenium MOF [Ru-3(BTC)(2)Y-y] . G(g) (BTC=benzene-1,3,5-tricarboxylate; Y=counter ions=Cl-, OH-, OAc-; G=guest molecules=HOAc, H2O) is modified via a mixed-linker approach, using mixtures of BTC and pyridine-3,5-d ...
Encapsulation of bimetallic metal nanoparticles into robust Zr-based metal-organic frameworks: Evaluation of the catalytic potential for size-selective hydrogenation

Rösler, Christoph; Dissegna, Stefano; López-Rechac, Víctor; Kauer, Max; Guo, Penghu; Turner, Stuart; Ollegot, Kevin; Kobayashi, Hirokazu; Yamamoto, Tomokazu; Peeters, Daniel; Wang, Yuemin; Matsumura, Syo; Van Tendeloo, Gustaaf; Kitagawa, Hiroshi; Muhler, Martin; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A. (John Wiley & Sons, 2017)

[EN] The realization of metal nanoparticles (NPs) with bimetallic character and distinct composition for specific catalytic applications is an intensively studied field. Due to the synergy between metals, most bimetallic ...
Loading of MOF-5 with Cu and ZnO Nanoparticles by Gas-Phase Infiltration with Organometallic Precursors: Properties of Cu/ZnO@MOF-5 as Catalyst for Methanol Synthesis

Müller, Maike; Hermes, Stephan; Kaehler, Kevin; van den Berg, Maurits W. E.; Muhler, Martin; Fischer, Roland A. (American Chemical Society, 2008-07-22)

The loading of [Zn(4)O(bdc)(3)] (MOF-5; bdc = 1,4-benzenedicarbocylate) with nanocrystalline Cu and ZnO species was achieved in a two-step process. First, the solvent-free gas-phase adsorption of the volatile precursors ...
Multifunktionale, Defekt-manipulierte Metall-organische Gerüste mit Rutheniumzentren: Sorption und katalytische Eigenschaften

Kozachuk, Olesia; Luz Mínguez, Ignacio; Llabrés i Xamena, Francesc Xavier; Noei, Heshmat; Kauer, Max; Bauke Albada, H.; Bloch, Eric D.; Marler, Bernd; Wang, Yuemin; Muhler, Martin; Fischer, Roland A. (Wiley, 2014-07-01)

[DE] Das Konzept der “festen Lösungen mit gemischten Linkern” (mixed-linker solid solution concept) ist angewendet worden, um die Metallzentren des gemischtvalenten RuII/III-Analogons der bekannten Familie der [M3II,II(btc)2]-MOFs ...
Nanometer-sized titania hosted inside MOF-5

Müller, Maike; Zhang, Xiaoning; Wang, Yuemin; Fischer, Roland A. (Royal Society of Chemistry, 2009)

[EN] Nanoscale titania particles were synthesized inside the porous coordination polymer [Zn(4)O(bdc)(3)] (bdc = 1,4-benzene-dicarboxylate, MOF-5) by adsorption of titanium isopropoxide from the gas-phase and subsequent ...
Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts

Luz Mínguez, Ignacio; Roesler, Christoph; Epp, Konstantin; Llabrés i Xamena, Francesc Xavier; Fischer, Roland A. (Wiley, 2015-08)

[EN] Host-guest inclusion properties of UiO-66 and UiO-67 metal-organic frameworks have been studied using ferrocene (FeCp2) as probe molecule. According to variable-temperature solid-state H-1 and C-13 CP-MAS-NMR, two ...
Ruthenium Metal–Organic Frameworks with Different Defect Types: Influence on Porosity, Sorption, and Catalytic Properties

Zhang, Wenhua; Kauer, Max; Halbherr, Olesia; Epp, Konstantin; Guo, Penghu; Gonzalez, Miguel I.; Xiao, Dianne J.; Wiktor, Christian; Llabrés i Xamena, Francesc Xavier; Woell, Christof; Wang, Yuemin; Muhler, Martin; Fischer, Roland A. (Wiley, 2016-09)

By employing the mixed-component, solid-solution approach, various functionalized ditopic isophthalate (ip) defect-generating linkers denoted 5-X-ipH(2), where X = OH (1), H (2), NH2 (3), Br (4), were introduced into the ...